566930-72-1

Basic information

• Product Name: Benzamide, 4-methoxy-N,N-bis[(1R)-1-phenylethyl]-
• CAS NO: 566930-72-1
• Molecular Formula: C24H25NO2
• Molecular Weight: 359.468
• Mol File: 566930-72-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzamide, 4-methoxy-N,N-bis[(1R)-1-phenylethyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzamide, 4-methoxy-N,N-bis[(1R)-1-phenylethyl]-(566930-72-1)
• EPA Substance Registry System: Benzamide, 4-methoxy-N,N-bis[(1R)-1-phenylethyl]-(566930-72-1)

Safety Data

• Hazardous Substances Data: 566930-72-1(Hazardous Substances Data)

Upstream product

• 68199-31-5 (R)-N-(α-methylbenzylidene)-α-methylbenzylamine 
• 98-86-2 acetophenone 
• 3886-69-9 (R)-1-phenyl-ethyl-amine 
• 40648-92-8 (R,R)-(+)-bis[alpha-methylbenzyl]amine hydrochloride 
• 100-07-2 4-methoxy-benzoyl chloride 

Relevant articles and documents

Synthesis of α-methyl kainic acid by stereospecific lithiation-dearomatizing cyclization of a chiral benzamide

Stereospecific lithiation of N-α-methylbenzyl benzamides gives configurationally stable tertiary benzyllithiums which undergo a stereospecific dearomatizing cyclization with >99% retention of stereochemistry. The products are partially saturated isoindolinones which carry a new fully-substituted stereogenic centre. A ten-step sequence converts one of these products to the α-methyl analogue of kainic acid.