682756-44-1

Basic information

• Product Name: Benzene, 1-iodo-4-[(4-methoxyphenyl)methoxy]-
• CAS NO: 682756-44-1
• Molecular Formula: C14H13IO2
• Molecular Weight: 340.161
• Mol File: 682756-44-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzene, 1-iodo-4-[(4-methoxyphenyl)methoxy]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-iodo-4-[(4-methoxyphenyl)methoxy]-(682756-44-1)
• EPA Substance Registry System: Benzene, 1-iodo-4-[(4-methoxyphenyl)methoxy]-(682756-44-1)

Safety Data

• Hazardous Substances Data: 682756-44-1(Hazardous Substances Data)

Upstream product

• 540-38-5 p-Iodophenol 
• 2746-25-0 p-Methoxybenzyl bromide 
• 824-94-2 p-methoxybenzyl chloride 

Downstream Products

• 682756-46-3 3-{4-[(4-methoxyphenyl)methoxy]phenyl}prop-2-yn-1-ol 
• 1059066-01-1 2-[4-[(4-methoxybenzyl)oxy]phenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 682756-52-1 (1E,3E,5E)-1-{4-[(4-methoxyphenyl)methoxy]phenyl}-6-phenylhexa-1,3,5-triene 
• 682756-48-5 (2E)-3-{4-[(4-methoxyphenyl)methoxy]phenyl}prop-2-en-1-ol 
• 682756-54-3 (1E,3E,5E)-1-(4-hydroxyphenyl)-6-phenyl-1,3,5-hexatriene 

Relevant articles and documents

Phosphorylated 1,6-diphenyl-1,3,5-hexatriene

A lipophilic dye consisting of a (1E,3E,5E)-1,6-diphenyl-1,3,5-hexatriene (DPH) fluorophore attached to a phosphate diester was prepared, and its fluorescence behavior in different solvent systems and in a liposomal membrane bilayer was examined. The key step in the synthesis of the functionalized end of the dye is a Sonogashira coupling of protected iodophenol with propargyl alcohol; the remaining phenyl ring and double bonds of the all-trans polyene core arise from a Wittig reaction with trans-cinnamaldehyde. Like DPH itself, the emission intensity of its phosphorylated derivative is quenched in polar media.