683-50-1Relevant articles and documents
METHOD FOR PRODUCING 3,3,3-TRIFLUOROPROPIONIC ACID CHLORIDE
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Page/Page column 13, (2009/01/24)
There is provided a process for producing 3,3,3-trifluoropropionyl chloride, which is characterized in that 3,3,3-trifluoropropionaldehyde is chlorinated by a chlorinating agent selected from the group consisting of chlorine (Cl2), sulfuryl chloride (SO2Cl2) and organic N-chloro compounds.
Kinetics of Oxidation of Methanol, Ethanol and n-Propanol by t-Butyl Hypochlorite
Kudesia, V. P.,Sharma, B. K.
, p. 82 - 83 (2007/10/02)
The kinetics of oxidation of ethanol (methanol or n-propanol) with t-BuOCl have been investigated at 40 deg C.The order of reaction is one each with respect to ethanol and t-BuOCl.The effect of ionic strength, and various metallic chlorides on the reaction rate has been studied.The various activation parameters have been evaluated.A mechanism involving ester formation is proposed.