68384-22-5

Basic information

• Product Name: 2-Naphthalenol, 2,3,4,4a,5,6,7,8-octahydro-4,4a-dimethyl-6-(1-methylethenyl)-, acetate, (2.alpha.,4.beta.,4a.beta.,6.alpha.)-
• Synonyms: 2-Naphthalenol, 2,3,4,4a,5,6,7,8-octahydro-4,4a-dimethyl-6-(1-methylethenyl)-, acetate, (2.alpha.,4.beta.,4a.beta.,6.alpha.)-
• CAS NO: 68384-22-5
• Molecular Formula: C₁₇H₂₆O₂
• Molecular Weight: 0
• Mol File: 68384-22-5.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-Naphthalenol, 2,3,4,4a,5,6,7,8-octahydro-4,4a-dimethyl-6-(1-methylethenyl)-, acetate, (2.alpha.,4.beta.,4a.beta.,6.alpha.)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Naphthalenol, 2,3,4,4a,5,6,7,8-octahydro-4,4a-dimethyl-6-(1-methylethenyl)-, acetate, (2.alpha.,4.beta.,4a.beta.,6.alpha.)-(68384-22-5)
• EPA Substance Registry System: 2-Naphthalenol, 2,3,4,4a,5,6,7,8-octahydro-4,4a-dimethyl-6-(1-methylethenyl)-, acetate, (2.alpha.,4.beta.,4a.beta.,6.alpha.)-(68384-22-5)

Safety Data

• Hazardous Substances Data: 68384-22-5(Hazardous Substances Data)

Upstream product

• 876-27-7 4-chlorophenyl acetate 
• 840474-83-1 4α,4aα-dimethyl-6β-(1-methylethenyl)-2,3,4,4a,5,6,7,8-octahydronaphthalene-2-ol 
• 4674-50-4 (+)-nootkatone 
• 10219-75-7 valencene 
• 64-19-7 acetic acid 

Downstream Products

• 50763-66-1 4α,4aα-dimethyl-6β-(1-methylethenyl)-2,3,4,4a,5,6,7,8-octahydronaphthalene-2β-ol 

Relevant articles and documents

+-Nootkatone derivative

The invention discloses a preparation method for +-nootkatone derivative. The present invention uses the +-nootkatone derivative extracted from cedar leaves as the main material, a chemical compound II is obtained after the restoration through sodium borohydride, the chemical compound II reacts to obtain a chemical compound III and a chemical compound IV through the decomposition of enzymatic dynamics, or decomposes through dynamic kinetics to obtain a chemical compound III with more than 90% yield, a chemical compound V is obtained after hydrolyzing the chemical compound III. The present invention turns the latent chiral ketone group in +-nootkatone into a chirality hydroxy center, and splits further; the present invention has the characteristics of being simple in operation, being high in product yield and with good optics purity.

Allylic oxidation of alkenes catalyzed by a copper-aluminum mixed oxide

A strategy for the allylic oxidation of cyclic alkenes with a copper-aluminum mixed oxide as catalyst is presented. The reaction involves the treatment of an alkene with a carboxylic acid employing tert-butyl hydroperoxide as the oxidant. In all cases, the corresponding allylic esters are obtained. When l-proline is employed, the allylic alcohol or ketone is obtained. The oxidation of cyclohexene and valencene has been optimized by design of experiments (DoE) statistical methodology.