68403-01-0Relevant academic research and scientific papers
SYNTHESIS AND REACTIONS OF SOME TRIPLE ALKOXO- AND THIOATO-BRIDGED ARENERUTHENIUM(II) COMPLEXES. X-RAY STRUCTURE DETERMINATION OF
Gould, R. O.,Stephenson, T. A.,Tocher, D. A.
, p. 375 - 384 (2007/10/02)
Reaction of 2> (arene = C6H6, 1,4-MeC6H4CHMe2) with NaNH2 in CH3CN gives a dark oil which upon treatment with ROH/NaBPh4 (R = Me, Et) gives the triple bridged complexes (BPh4>.The structure of the benzene complex (R = Me) has been verified by X-ray analysis.The crystals are monoclinic, space group P21/n with a 11.725(4), b 15.573(5), c 18.739(2) Angstroem; β 103.29(2)deg.These complexes undergo reactions with tertiary phosphines and hydrogen halides.There is also spectroscopic evidence for intermolecular exchange of the bridging alkoxo ligands on mixing pure solutions of the + cations (M = Ru, Os).Reaction of 2> with Pb(SEt) 2 in CH3CN gives the analogous + cations.
SYNTHESIS OF BINUCLEAR HYDROXO- AND ALKOXO-BRIDGED ARENE COMPLEXES OF RUTHENIUM(II) AND OSMIUM(II)
Arthur, T.,Robertson, D.R.,Tocher, D.A.,Stephenson, T.A.
, p. 389 - 400 (2007/10/02)
Reactions of aqueous solutions of 2> (M = Ru, Os) with an excess of either NaOH or Na2CO3 followed by addition of NaBPh4 gave as the major product BPh4 together with some BPh4.Recryst
