68485-14-3Relevant articles and documents
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Adkins et al.
, p. 5401,5403 Anm. 13 (1950)
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C-H bond arylations and benzylations on oxazol(in)es with a palladium catalyst of a secondary phosphine oxide
Ackermann, Lutz,Barfuesser, Sebastian,Kornhaass, Christoph,Kapdi, Anant R.
scheme or table, p. 3082 - 3085 (2011/08/07)
An air-stable, well-defined palladium complex derived from secondary phosphine oxide (SPO) (1-Ad)2P(O)H enabled efficient C-H bond functionalizations with ample scope, which set the stage for direct arylations and benzylations of (benz)oxazoles, as well as unprecedented palladium-catalyzed C-H bond arylations on nonaromatic oxazolines.
Direct palladium-catalyzed alkenylation, benzylation and alkylation of ethyl oxazole-4-carboxylate with alkenyl-, benzyl- and alkyl halides
Verrier, Cecile,Hoarau, Christophe,Marsais, Francis
supporting information; experimental part, p. 647 - 650 (2009/06/20)
The ethyl oxazole-4-carboxylate was directly and regioselectively alkenylated, benzylated and alkylated with alkenyl-, benzyl-, allyl- and alkyl halides in the presence of catalytic amounts of palladium acetate with caesium carbonate using Buchwald's John