685507-97-5Relevant academic research and scientific papers
Highly diastereoselective Henry reaction of nitro compounds with chiral derivatives of glyoxylic acid
Kudyba, Iwona,Raczko, Jerzy,Urbańczyk-Lipkowska, Zofia,Jurczak, Janusz
, p. 4807 - 4820 (2004)
N-Glyoxyloyl-(2R)-bornane-10,2-sultam and (1R)-8-phenylmenthyl glyoxylate react stereoselectively with simple nitro compounds giving diastereoisomeric nitroalcohols with high asymmetric induction. N-Glyoxyloyl-(2R)-bornane-10,2- sultam 1a is shown to be a
Asymmetric Nitroaldol Reaction. Synthesis of Taxotere Side Chain and (-)-Bestatin Using (1R)-8-Phenylmenthyl Glyoxylate
Kudyba, Iwona,Raczko, Jerzy,Jurczak, Janusz
, p. 2844 - 2850 (2007/10/03)
The nitroaldol reaction of (1R)-8-phenylmenthyl glyoxylate (3b) with 1-nitro-1-phenylmethane (4) or with 1-nitro-2-phenylethane (13) led stereoselectively to adducts syn-2b and syn-12b, which were then transformed into the Taxotere side chain and (-)-best
