686-39-5Relevant academic research and scientific papers
[N(CF3)2], effect of fluorine substituents on aryl groups of iodonium cations and of coordinating bases on the fluoride transfer from the anion to the cation
Hirschberg, Markus E.,Wenda, André,Frohn, Hermann-Josef,Ignat'Ev, Nikolai V.
, p. 24 - 27 (2012)
Three prototypical fluoroaryliodonium salts with the [N(CF 3)2]- anion were obtained by metathesis in the corresponding tetrafluoroborate salts [Ar(Ar′)I][BF4] (Ar/Ar′ = C6H5/4-FC6/su
A convenient synthesis of N,N-bis(trifluoromethyl)anilines
Hirschberg,Ignat'Ev,Wenda,Frohn,Willner
body text, p. 176 - 182 (2012/03/27)
A convenient synthesis of N,N-bis(trifluoromethyl)anilines by means of dediazotation reactions of previously unknown aryldiazoniumbis(trifluoromethyl) imides in the presence of CuI salts are described. Properties and applications of N,N-bis(trifluoromethyl)anilines in syntheses of aromatic compounds containing the (CF3)2N group are presented.
