432-03-1Relevant articles and documents
HEXA-, HEPTA- UND OCTAFLUORTRIMETHYLAMIN
Buerger, H.,Niepel, H.,Pawelke, G.,Frohn, H. J.,Sartori, P.
, p. 231 - 238 (1980)
The electrofluorination of N(CH3)3 yields, along with fragmentation and recombination products and N(CF3)3 (I), minor quantities of the hitherto unknown compounds (CF3)2NCF2H (II), CF3N(CF2H)2 (III) and N(CF2H)3 (IV).I-IV have been isolated and characterized by their (1)H, (13)C and (19)F nmr and their EI and CI mass spectra.
Mechanistic studies on the electrochemical fluorination of trialkylamines and tetraalkylammonium salts
Dimitrov,Pfeifer,Jonethal,Ruediger,Seppelt
, p. 143 - 150 (2007/10/03)
The comparative electrochemical fluorination (ECF) of selected trialkylamines and tetraalkylammonium salts was studied in order to obtain experimental data allowing a precise valuation of the ECF mechanism. The results of the investigation favour the ECF mechanism already proposed by Simons, via oxidation of F- .(HF)n to F and nHF, as probably the only relevant electrochemical process at the anode. For the first time some experimental proof has been obtained that a direct electrochemical oxidation of the substrate can be ruled out as a decisive step in ECF.
