687-46-7Relevant academic research and scientific papers
Synthesis and reactivity of α and β-chloro-α-phenylselanyl esters
Lebarillier, Loic,Outurquin, Francis,Paulmier, Claude
, p. 7495 - 7502 (2007/10/03)
Thermal decomposition of the dichloro-adducts derived from α-phenylselanylesters 1, 2 and 4 has been studied. N-Chloro-succinimide treatment of esters 2 was an efficient preparative method for α-chloro-α-phenylselanylesters 10 and α-chloro-α,β-unsaturated esters 11. Some transformations of esters 10 were achieved, α,β-Dichloro-α-phenylselanylesters 22 were prepared from β-chloro-α-phenylselanylesters 5 or by decomposition of the dichloroselenuranes 21 derived from esters 4. (C) 2000 Elsevier Science Ltd.
Reaction of Benzeneseleninyl Chloride with Olefins in the Presence of a Lewis Acid. A Novel One Step Vinylic Chlorination
Kamigata, Nobumasa,Satoh, Takeshi,Yoshida, Masato
, p. 449 - 454 (2007/10/02)
In the presence of aluminum chloride benzeneseleninyl chloride was found to be an exellent vinylic chlorinating reagent of olefins under mild conditions.However, such olefins as styrene, trans-stilbene, and trans-1-phenylpropene afforded dichloro adducts under similar conditions.A plausible reaction mechanism involving positive chlorine intermediate is proposed.
