6874-45-9Relevant academic research and scientific papers
TITANKOMPLEXE OFFENKETTIGER UND CYCLISCHER ARSANLIGANDEN: SYNTHESE UND KATALYTISCHE WIRKUNG (1)
Kauffmann, Thomas,Ennwn, Johann,Berghus, Karlheinz
, p. 1971 - 1974 (1984)
The Ti(IV) complexes 1b, 2b, and 6 have been synthesized from new multi-electron ligands. 2b, after reduction with Et2AlCl, dimerizes isoprene mainly to 8c and trimerizes butadiene mainly to ttt-CDT.Ti(IV) compounds of the macrocyclic ligands 7a-c exhibit the same catalytic properties after reduction with Et2AlCl.
