TITANKOMPLEXE OFFENKETTIGER UND CYCLISCHER ARSANLIGANDEN: SYNTHESE UND KATALYTISCHE WIRKUNG (1)

DOI: 10.1016/S0040-4039(01)90089-9

Source and publish data:

Tetrahedron Letters p. 1971 - 1974 (1984)

Update date:2022-08-04

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Authors:

Kauffmann, Thomas

Ennwn, Johann

Berghus, Karlheinz

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Article abstract of DOI:10.1016/S0040-4039(01)90089-9

The Ti(IV) complexes 1b, 2b, and 6 have been synthesized from new multi-electron ligands. 2b, after reduction with Et2AlCl, dimerizes isoprene mainly to 8c and trimerizes butadiene mainly to ttt-CDT.Ti(IV) compounds of the macrocyclic ligands 7a-c exhibit the same catalytic properties after reduction with Et2AlCl.

Full text of DOI:10.1016/S0040-4039(01)90089-9

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