
Tetrahedron Letters p. 1971 - 1974 (1984)
Update date:2022-08-04
Topics:
Kauffmann, Thomas
Ennwn, Johann
Berghus, Karlheinz
The Ti(IV) complexes 1b, 2b, and 6 have been synthesized from new multi-electron ligands. 2b, after reduction with Et2AlCl, dimerizes isoprene mainly to 8c and trimerizes butadiene mainly to ttt-CDT.Ti(IV) compounds of the macrocyclic ligands 7a-c exhibit the same catalytic properties after reduction with Et2AlCl.
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(1978)