688034-91-5

Basic information

• Product Name: Silane, (1,1-dimethylethyl)[[(1R)-1-methyl-3-butenyl]oxy]diphenyl-
• CAS NO: 688034-91-5
• Molecular Formula: C21H28OSi
• Molecular Weight: 324.538
• Mol File: 688034-91-5.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Silane, (1,1-dimethylethyl)[[(1R)-1-methyl-3-butenyl]oxy]diphenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, (1,1-dimethylethyl)[[(1R)-1-methyl-3-butenyl]oxy]diphenyl-(688034-91-5)
• EPA Substance Registry System: Silane, (1,1-dimethylethyl)[[(1R)-1-methyl-3-butenyl]oxy]diphenyl-(688034-91-5)

Safety Data

• Hazardous Substances Data: 688034-91-5(Hazardous Substances Data)

Upstream product

• 64584-92-5 (R)-pent-4-en-2-ol 
• 58479-61-1 tert-butylchlorodiphenylsilane 

Downstream Products

• 1233961-23-3 ((4S,5S)-5-((R)-2-hydroxypropyl)-2,2-dimethyl-1,3-dioxolan-4-yl)methyl 4-methylbenzenesulfonate 
• 303044-39-5 ethyl (2E,5R)-5-{[(tert-butyl)(diphenyl)silyl]oxy}hex-2-enoate 
• 303044-41-9 (2R,3R)-3-{(2R)-2-{[(1,1-dimethylethyl)diphenylsilyl]oxy}propyl}oxirane-2-methanol 
• 303044-40-8 (2E,5R)-5-{[(1,1-dimethylethyl)diphenylsilyl]oxy}hex-2-en-1-ol 
• 183310-90-9 (R)-3-(tert-butyl-diphenyl-silanyloxy)-butyraldehyde 
• 1354689-55-6 (5R,7R)-7,10,10-trimethyl-9,9-diphenyl-5-vinyl-2,4,8-trioxa-9-silaundecane 
• 1354689-50-1 (5S,7R)-7,10,10-trimethyl-9,9-diphenyl-5-vinyl-2,4,8-trioxa-9-silaundecane 

Relevant articles and documents

Carbohydrate/DBU Cocatalyzed Alkene Diboration: Mechanistic Insight Provides Enhanced Catalytic Efficiency and Substrate Scope

A mechanistic investigation of the carbohydrate/DBU cocatalyzed enantioselective diboration of alkenes is presented. These studies provide an understanding of the origin of stereoselectivity and also reveal a strategy for enhancing reactivity and broadening the substrate scope.

Stereoselective total synthesis of ophiocerin C through two different approaches

Stereoselective total synthesis of ophiocerin C has been accomplished through two different approaches starting separately from acetaldehyde and from (R)-propylene oxide, and Sharpless asymmetric dihydroxylation has been employed as the key step in both a

A practical, stereospecific route to 18-, 19-, and 20-hydroxyeicosa-5(Z), 8(Z),11(Z),14(Z)-tetraenoic acids (18-, 19-, and 20-HETEs)

Suzuki-Miyaura cross-coupling of cis-vinylbromide 6, obtained in three steps from diol 4, with functionalized boranes provides a practical, stereospecific route to the title CYP P450 eicosanoids.