68896-35-5Relevant academic research and scientific papers
Desymmetrization of Phosphinic Acids via Pd-Catalyzed Asymmetric Allylic Alkylation: Rapid Access to P-Chiral Phosphinates
Trost, Barry M.,Spohr, Simon M.,Rolka, Alessa B.,Kalnmals, Christopher A.
, p. 14098 - 14103 (2019/10/11)
The synthesis of P-chiral compounds is challenging, especially since useful catalytic methods for preparing such molecules are scarce. Herein we disclose a desymmetrization that employs phosphinic acids as prochiral nucleophiles in a Pd-catalyzed asymmetr
Allylic phosphinates via palladium-catalyzed allylation of H-phosphinic acids with allylic alcohols
Coudray, Laetitia,Bravo-Altamirano, Karla,Montchamp, Jean-Luc
supporting information; body text, p. 1123 - 1126 (2009/04/07)
A novel catalytic allylation of H-phosphinic acids is described. Using Pd/xantphos (2 mol %), H-phosphinic acids react directly with allylic alcohols to produce P-allylated disubstituted phosphinic acids.
Facile synthesis of functionalised phenylphosphinic acid derivatives
Boyd, E. Andrew,Boyd, Mark E.K.,Loh Jr., Vincent M.
, p. 1651 - 1654 (2007/10/03)
Functionalised phenylphosphinic acid derivatives have been synthesised by addition of bis(trimethylsilyl)phenylphosphinite 2 to a series of electrophiles.
