68914-36-3Relevant academic research and scientific papers
Highly luminescent copper(i) halide complexes chelated with a tetradentate ligand (PNNP): Synthesis, structure, photophysical properties and theoretical studies
Jia, Ji-Hui,Chen, Xu-Lin,Liao, Jian-Zhen,Liang, Dong,Yang, Ming-Xue,Yu, Rongmin,Lu, Can-Zhong
supporting information, p. 1418 - 1426 (2019/01/29)
Two emissive copper(i) halide complexes (PNNP)Cu2Br2 (1) and (PNNP)Cu2I2 (2), which are constructed from butterfly-shaped dinuclear Cu2X2 cores and a new tetradentate ligand (PNNP = 1,3-bis
Synthesis and thermal behavior of dimethyl scandium complexes featuring anilido-phosphinimine ancillary ligands
Conroy, Korey D.,Piers, Warren E.,Parvez, Masood
, p. 834 - 846 (2008/03/30)
A family of N,N donor ligands [1-(NHAr)-2-(PR2{double bond, long}NAr′)C6H4] (1a-d; Ar = 2,6-iPr2-C6H3, R = Me, Ph, Ar′ = 2,4,6-Me3-C6H2, 2-iPr-C6H4, 2,6-iPr2-C6H3) has been prepared and fully characterized by multinuclear NMR spectroscopy and X-ray crystallography. Lithiation of the N-H unit and subsequent salt metathesis protocols with ScCl3THF3 provides an avenue to organometallic scandium complexes. The resultant base-free monomeric dichlorides LScCl2, 3a-d, have been fully characterized by NMR spectroscopy as well as X-ray crystallography (3a,c,d). Alkylation of the dichlorides using LiMe results in clean formation of dialkyl complexes LScMe2 4a-c. Thermolysis of these materials under argon and hydrogen leads to decomposition products as a result of C-H activation of the ligand. Analysis of these results provides a qualitative assessment of the metalative resistance of each ligand framework.
SYNTHESE UND NMR-UNTERSUCHUNGEN VON 2-FLUOR-TRIPHENYLPHOSPHINEN UND IHREN DERIVATEN
Stegmann, H. B.,Kuehne, H.-M.,Wax, G.,Scheffler, K.
, p. 331 - 336 (2007/10/02)
2-Fluorophenyllithium reacts with chloro-phenyl-phosphines PH3-nPCln, n=1,2,3 to give diphenyl-(2-fluorophenyl)phosphine 1, bis-(2-fluorophenyl)phenyl-phosphine 2 and tris-(2-fluorophenyl)phosphine 3.The new compounds and their oxide
