68965-51-5

Upstream product

• 451-40-1 phenyl benzyl ketone 
• 931-51-1 cyclohexylmagnesiumchloride 
• 855363-72-3 2-cyclohexyl-1,2-diphenyl-ethanol 
• 931-50-0 cyclohexylmagnesium bromide 
• 712-50-5 Cyclohexyl phenyl ketone 
• 6921-34-2 benzylmagnesium chloride 
• 104722-26-1 trans-1,2-dibenzoylcyclohexane 
• 2719-27-9 cyclohexanylcarbonyl chloride 
• 71-43-2 benzene 
• 87100-15-0 cyclohexylboronic acid pinacol ester 
• 1439-07-2 trans-Stilbene oxide 

Downstream Products

• 712-50-5 Cyclohexyl phenyl ketone 
• 100-52-7 benzaldehyde 

Relevant academic research and scientific papers

Iterative synthesis of alkenes by insertion of lithiated epoxides into boronic esters

The insertion of lithiated epoxides into boronic esters followed by thermal syn-elimination provides a stereospecific entry to alkenes. This process avoids transition metals and is amenable to iteration to provide higher substitution patterns.

Zinc-promoted reactions. 8. The effect of ring strain in the reduction of 1,2-dibenzoylcycloalkanes

Ring cleavage was the main route in the Zn reduction of 1 in neat AcOH, while selective carbonyl reduction predominated in the presence of LiCl. The less strained 2 underwent only carbonyl reduction with Zn/AcOH. The Clemmensen reduction of both 1 and 2 resulted mainly in acyclic products. The unstrained 3 was fairly resistant towards reduction, and did not undergo ring cleavage.