6898-67-5Relevant academic research and scientific papers
n,?-Conjugation in N-methylvinylamine. A photoelectron spectroscopic study
Fang, Jiye,Sim, Cher Whee,Mok, Chup Yew,Huang, Hsing Hua,Novak, Igor
, p. 1625 - 1628 (2007/10/02)
The unstable species N-methylvinylamine was prepared by the thermal decomposition of gaseous 2-methylaziridine in a flow system its UV photoelectron spectrum was recorded.The first two bands were observed at 8.00 and 11.00 eV.The methyl substituent shows the effect of reducing the degree of conjugation between the nN and ?CC orbitals, as revealed by a comparison with the spectrum of the parent compound vinylamine.
Carbene Reactions, XVII. Nitrile Ylides via 1,1-Elimination
Hoffmann, Reinhard W.,Barth, Wolfgang
, p. 634 - 642 (2007/10/02)
The 3-aminoquadricyclane-3-carbonitrile 7 decomposed upon vapor phase thermolysis into benzene and cyano(dimethylamino)carbene 15.Thermolysis of the corresponding benzylidene derivative 20 liberated the 1,3-dipole 21, which eventually leads to 1-isoindolecarbonitrile 23.The nitrile ylide 26 liberated similarly furnished the bicyclic compound 27 via intramolecular 1,3-dipolar addition.
