69090-75-1Relevant academic research and scientific papers
Kinetic study of the thermal decomposition on bis(dialkyldithiocarbamate) Cd(II) complexes by isothermal and non-isothermal thermogravimetry
Nobrega Machado, Maria C.,Magalha?es Nunes, Liliane,Davidson Pinheiro, Carlos,Caetano MacHado, Jose?,Gouveia Souza, Antonio
, p. 201 - 207 (1999)
The thermal decomposition kinetics of solid Cd(S2CNR2)2 complexes, where R=C2H5, n-C3H7, n-C4H9 and iso-C4H9, has been studied using i
Volatile Mixed-Ligand Complexes of Bis(diisobutyldithiocarbamato)cadmium with 1,10-Phenanthroline, 2,2′-Bipyridyl, and 4,4′-Bipyridyl: Crystal and Molecular Structure of the Cd[S2CN(i-C4H9)2]2(C 12H8N2) Complex
Zemskova,Prashad, Ganga,Glinskaya,Klevtsova,Durasov,Tkachev,Gromilov,Larionov
, p. 1525 - 1531 (2008/10/08)
Cadmium(II) diisobutyldithiocarbamate Cd[S2CN(i-C4H9)2]2 reacts with 1,10-phenanthroline (Phen), 2,2′-bipyridine (2,2′-Bipy), or 4,4′-bipyridine (4,4′-Bipy) to produce the volatile mixed-ligand complexes CdL2B (L = (i-C4H9)2NCS-2; B = Phen, 2,2′-Bipy) or Cd2L4(4,4′-Bipy). X-ray crystallography indicates that Cd[S2CN(i-C4H9)2]2Phen has a mononuclear molecular structure with a distorted octahedral CdS4N2 coordination core formed by the bidentate chelate ligands L and Phen. All the complexes are quantitatively sublimated upon heating in vacuum (T = 50-300°C, p ～ 10-3 mm Hg) and form γ-CdS as a result of thermal decomposition in air.
