69125-80-0

Basic information

• Product Name: 1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluorododecane
• Synonyms: 1,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluorododecane; 1-Hexylperfluorohexane; dodecane, 1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluoro-
• CAS NO: 69125-80-0
• Molecular Formula: C₁₂H₁₃F₁₃
• Molecular Weight: 404.2109
• Mol File: 69125-80-0.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 213.3°C at 760 mmHg
• Flash Point: 81.2°C
• Density: 1.357g/cm³
• Vapor Pressure: 0.241mmHg at 25°C
• Refractive Index: 1.323
• CAS DataBase Reference: 1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluorododecane(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluorododecane(69125-80-0)
• EPA Substance Registry System: 1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluorododecane(69125-80-0)

Safety Data

• Hazardous Substances Data: 69125-80-0(Hazardous Substances Data)

Upstream product

• 2043-57-4 1,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluoro-8-iodooctane 
• 693-04-9 butyl magnesium bromide 
• 592-41-6 1-hexene 
• 355-43-1 n-perfluorohexyl iodide 
• 335-56-8 1-bromo-1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluorohexane 
• 355-41-9 perfluoro-n-hexyl chloride 
• 120695-82-1 1,1,1,2,2,3,3,4,4,5,5,6,6-tridecafluoro-8-iodododecane 

Relevant articles and documents

PROCESS FOR THE PREPARATION OF SEMIFLUORINATED ALKANES USING GRIGNARD REAGENTS

The present invention provides a method for preparing a compound of formula (I) F-(CF2)n-(CH2)m-Ro (I), wherein n is an integer from 2 to 12, m is an integer from 0 to 7, Ro is a linear or branched saturated alkyl group and o depicts the number of carbon atoms, o is an integer from 1 to 12, and wherein m+o is an integer from 2 to 12; comprising reacting a fluorinated compound of formula (II) F-(CF2)n-(CH2)m-X (II), wherein X is CI, Br, I, MgCl, MgBr, or Mgl, and n and m have the same meaning as in formula (I), with a non-fluorinated compound of formula (III) Ro-Y (III), wherein Y is CI, Br, I, MgCl, MgBr, or Mgl, with the proviso that when X is CI, Br or I, Y is MgCl, MgBr or Mgl, and when X is MgCl, MgBr or Mgl, Y is CI, Br or I, and Ro has the same meaning as in formula (I).

Nickel(0)-catalyzed fluoroalkylation of alkenes, alkynes, and aromatics with perfluoroalkyl chlorides

Treatment of perfluoroalkyl chlorides (RFCl) with alkenes, alkynes, or aromatics in the presence of 0.1 equiv of nickel dichloride, 1.5 equiv of zinc powder, and 0.4 equiv of triphenylphosphine in DMF at 95-100 °C for 6-8 h give the correspondi