691869-52-0

Upstream product

• 34170-81-5 diethyl (2-chloro-2-oxoethyl)phosphonate 
• 691869-51-9 (2E,9E,11E)-(4R,5S,6S,8S,13R,14R)-15-((1S,3R,4S)-3,4-Bis-triethylsilanyloxy-cyclopentyl)-4-methoxy-1-(4-methoxy-benzyloxy)-3,5,9,13-tetramethyl-14-triethylsilanyloxy-8-triisopropylsilanyloxy-pentadeca-2,9,11-trien-6-ol 
• 3095-95-2 diethylphosphonoacetic acid 
• 691869-44-0 (E)-(2R,3R)-3-Hydroxy-6-(4-methoxy-benzyloxy)-2,4-dimethyl-hex-4-enoic acid methoxy-methyl-amide 
• 691869-45-1 (E)-(2R,3R)-3-Methoxy-6-(4-methoxy-benzyloxy)-2,4-dimethyl-hex-4-enoic acid methoxy-methyl-amide 
• 1026620-20-1 4-Nitro-benzoic acid (E)-(1S,2S,3R)-3-methoxy-6-(4-methoxy-benzyloxy)-2,4-dimethyl-1-((E)-(S)-3-methyl-5-oxo-2-triisopropylsilanyloxy-pent-3-enyl)-hex-4-enyl ester 
• 1027202-98-7 4-Nitro-benzoic acid (E)-(1S,2S,3R)-1-[(E)-(S)-5-(tert-butyl-dimethyl-silanyloxy)-2-hydroxy-3-methyl-pent-3-enyl]-3-methoxy-6-(4-methoxy-benzyloxy)-2,4-dimethyl-hex-4-enyl ester 
• 691869-49-5 (2R,3R)-4-((1S,3R,4S)-3,4-Bis-triethylsilanyloxy-cyclopentyl)-2-methyl-3-triethylsilanyloxy-butan-1-ol 
• 691869-33-7 (R)-4-Benzyl-3-[(E)-(2R,3R)-3-hydroxy-6-(4-methoxy-benzyloxy)-2,4-dimethyl-hex-4-enoyl]-oxazolidin-2-one 
• 691869-37-1 (S)-3-((2S,3R)-5-Allyl-2-methyl-3-triethylsilanyloxy-oct-7-enoyl)-4-isopropyl-oxazolidin-2-one 
• 691869-38-2 (S)-3-((2S,3R)-4-Cyclopent-3-enyl-2-methyl-3-triethylsilanyloxy-butyryl)-4-isopropyl-oxazolidin-2-one 
• 691869-47-3 (S)-3-((2S,3R)-5-Allyl-3-hydroxy-2-methyl-oct-7-enoyl)-4-isopropyl-oxazolidin-2-one 
• 197227-70-6 (2E)-4-[(4-methoxybenzyl)oxy]-2-methylbut-2-enal 
• 147438-60-6 (E)-(2R,3R)-3-Methoxy-6-(4-methoxy-benzyloxy)-2,4-dimethyl-hex-4-enal 

Downstream Products

• 691869-54-2 (3E,10E,12E)-(1R,7S,9S,14R,15R)-7-[(E)-(1S,2R)-2-Methoxy-5-(4-methoxy-benzyloxy)-1,3-dimethyl-pent-3-enyl]-10,14-dimethyl-9-triisopropylsilanyloxy-6,16-dioxa-bicyclo[13.3.1]nonadeca-3,10,12-triene-5,17-dione 
• 691869-42-8 (Diethoxy-phosphoryl)-acetic acid (4E,6E)-(1S,3S,8R)-1-[(E)-(1S,2R)-2-methoxy-5-(4-methoxy-benzyloxy)-1,3-dimethyl-pent-3-enyl]-4-methyl-8-[(2R,4S)-6-oxo-4-(2-oxo-ethyl)-tetrahydro-pyran-2-yl]-3-triisopropylsilanyloxy-nona-4,6-dienyl ester 
• 691869-41-7 (Diethoxy-phosphoryl)-acetic acid (4E,6E)-(1S,3S,8R,9R)-10-((1S,3R,4S)-3,4-dihydroxy-cyclopentyl)-9-hydroxy-1-[(E)-(1S,2R)-2-methoxy-5-(4-methoxy-benzyloxy)-1,3-dimethyl-pent-3-enyl]-4,8-dimethyl-3-triisopropylsilanyloxy-deca-4,6-dienyl ester 

Relevant academic research and scientific papers

Stereoselective Total Synthesis of Antitumor Macrolide (+)-rhizoxin D

A convergent, stereoselective total synthesis of the macrolide antitumor agent rhizoxin D is described. (+)-DIPCI-promoted asymmetric aldol reaction, Evans-Tishchenko 1,3-diol synthesis, modified Julia coupling, and Horner-Wadsworth-Emmons reactions are featured.