691884-18-1

Basic information

• Product Name: 1-bromo-3,5-bis(imidazole-1-ylmethyl)benzene
• Synonyms: 1-bromo-3,5-bis(imidazole-1-ylmethyl)benzene
• CAS NO: 691884-18-1
• Molecular Weight: 317.188
• Mol File: 691884-18-1.mol

Chemical Properties

• CAS DataBase Reference: 1-bromo-3,5-bis(imidazole-1-ylmethyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-bromo-3,5-bis(imidazole-1-ylmethyl)benzene(691884-18-1)
• EPA Substance Registry System: 1-bromo-3,5-bis(imidazole-1-ylmethyl)benzene(691884-18-1)

Safety Data

• Hazardous Substances Data: 691884-18-1(Hazardous Substances Data)

Upstream product

• 288-32-4 1H-imidazole 
• 51760-23-7 1-bromo-3,5-bis(bromomethyl)benzene 
• 108835-03-6 1-bromo-3,5-bis(chloromethyl)benzene 
• 99-27-4 dimethyl 5-aminoisophthalate 
• 51760-21-5 dimethyl 5-bromoisophthalate 
• 51760-22-6 5-bromo-1,3-dihydroxymethylbenzene 
• 556-96-7 5-bromo-1,3-xylene 

Downstream Products

• 782479-66-7 1-(1-imidazolyl)-3,5-bis(imidazol-1-ylmethyl)benzene 

Relevant articles and documents

Syntheses, crystal structures and anion-exchange properties of copper(II) and cadmium(II) complexes containing a novel tripodal ligand

Four novel metal-organic frameworks (MOFs), [Cu(3)2](ClO 4)2 · 0.67H2O (4), [Cu(3) 2][Cu(mal)2] · 6H2O (mal2- = -OCOCH2COO-) (5), [Cd(3)2](NO 3)2 · H2O, (6) and [Cd(3)(OAc) 2] · 6H2O (7), were obtained by self-assembly of the corresponding metal salts with a novel flexible tripodal ligand, 1-(1-imidazolyl)-3,5-bis(imidazol-1-ylmethyl)benzene (3), and their structures were determined by single crystal X-ray diffraction analyses. Complex 4 has a 2D network structure in which 3 shows two different coordination modes, one kind of 3 acts as a three-connecting ligand and the other one serves as a two-connecting (bridging) ligand using its two flexible arms. Complex 5 has an infinite 1D hinged chain structure in which only two of three imidazole groups of 3 are coordinated with the metal atoms while the last one is uncoordinated. In complexes 6 and 7, the metal centers are all six-coordinated; 6 has a 2D honeycomb and 7 has a 2D grid network structure, respectively. Ligand 3 has a trans conformation in 7, which is different from that in complexes 4 (cis and L-shaped), 5 (cis) and 6 (cis). The anion-exchange properties of complex 6 were investigated.

ZINC COMPLEX

A zinc complex characterized in exhibiting an octahedral structure and being configured from repeating units represented by general formula (I): wherein L represents a linker region, and R1 represents a C1-4 alkyl group, which can have a halogen atom.