692-85-3

Basic information

• Product Name: 10-Ketomyristic acid methyl ester
• Synonyms: 10-Ketomyristic acid methyl ester;10-Oxomyristic acid methyl ester;10-Oxotetradecanoic acid methyl ester
• CAS NO: 692-85-3
• Molecular Weight: 0
• Mol File: 692-85-3.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 10-Ketomyristic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 10-Ketomyristic acid methyl ester(692-85-3)
• EPA Substance Registry System: 10-Ketomyristic acid methyl ester(692-85-3)

Safety Data

• Hazardous Substances Data: 692-85-3(Hazardous Substances Data)

Upstream product

• 106-79-6 dimethyl sebacate 
• 818-88-2 sebacic acid mono methyl ester 
• 71778-79-5 trans-1,2-Cyclohexandiyl-1-(4-benzoylbenzoat)-2-tetradecanoat 
• 77-76-9 2,2-dimethoxy-propane 
• 71638-22-7 1,2-Ethandiyl-1-(4-benzoylbenzoat)-2-tetradecanoat 
• 71778-78-4 o-Phenylen-1-(4-benzoylbenzoat)-2-myristat 
• 14065-32-8 methyl 10-chloro-10-oxodecanoate 
• 1119-90-0 di-n-butylzinc 
• 109-65-9 1-bromo-butane 

Downstream Products

• 675-95-6 10-oxotetradecanoic acid 

Relevant articles and documents

Regioselective Functionalization of Non-Activated CH-bonds, 2. Photochemical Functionalization of the Myristoyl Group in 1,2-Alkanediyl and o-Phenylene 1-(4-Benzoylbenzoate) 2-Myristates

Myristic acid (1a) was linked with ethylene glycol (2a), trans-1,2-cyclohexanediol (2b), and catechol (2c) to 4-benzoylbencoic acid to form the diesters 4a-c.These cyclize by photolysis to the carbinols 12, which are converted into the methyl 7- to 13-oxomyristates (5a).The ketofunctionalization of the remote CH2-groups in 1a is more selective than in the corresponding benzoylbenzoic esters 13 without the 1,2-alkanediyl or o-phenylene link.Additionally the maximum of the functionalization is shifted from the end towards the middle of the chain.The latter observation can be explained by a higher population of gauche conformations at the beginning of the chain.In CCl4 the selectivity increases slightly from 4a to 4b, c with increasing rigidity of the link.The polarity of the solvent has only a small effect on the selectivity.