69221-99-4Relevant articles and documents
Enzyme-substrate complementarity governs access to a cationic reaction manifold in the P450BM3-catalysed oxidation of cyclopropyl fatty acids
Cryle, Max J.,Hayes, Patricia Y.,De Voss, James J.
, p. 15994 - 15999 (2013/02/21)
The products of cytochrome P450BM3-catalysed oxidation of cyclopropyl-containing dodecanoic acids are consistent with the presence of a cationic reaction intermediate, which results in efficient dehydrogenation of the rearranged probes by the enzyme. These results highlight the importance of enzyme-substrate complementarity, with a cationic intermediate occurring only when the probes used begin to diverge from ideal substrates for this enzyme. This also aids in reconciling literature reports supporting the presence of cationic intermediates with certain cytochrome P450 enzyme/substrate pairs.
Synthesis of dodec-10E-Enyl acetate - The sex pheromone of phyllonorycter blancardella (Lepidoptera: Gracillariidae)
Ishchenko
, p. 77 - 79 (2007/10/03)
Dodec-10E-enyl acetate has been synthesized from undecenoic acid. Field trials have shown its high attractiveness for Phyllonorycter blancardella males. 1996 Plenum Publishing Corporation.
