6933-30-8

Basic information

• Product Name: Methanone, (2-fluorophenyl)-2-thienyl-
• CAS NO: 6933-30-8
• Molecular Formula: C11H7FOS
• Molecular Weight: 206.24
• Mol File: 6933-30-8.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Methanone, (2-fluorophenyl)-2-thienyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Methanone, (2-fluorophenyl)-2-thienyl-(6933-30-8)
• EPA Substance Registry System: Methanone, (2-fluorophenyl)-2-thienyl-(6933-30-8)

Safety Data

• Hazardous Substances Data: 6933-30-8(Hazardous Substances Data)

Upstream product

• 5713-61-1 thiophen-2-yl magnesium bromide 
• 393-52-2 2-Fluorobenzoyl chloride 
• 188290-36-0 thiophene 
• 5271-67-0 2-Thiophenecarbonyl chloride 
• 348-52-7 1-Fluoro-2-iodobenzene 

Downstream Products

• 623580-54-1 1-(o-fluorophenyl)-1-(thiophene-2-yl)-prop-2-yn-1-ol 
• 860016-98-4 (2-fluorophenyl)-(thiophen-2-yl)methanol 

Relevant articles and documents

Continuous flow synthesis of diaryl ketones by coupling of aryl Grignard reagents with acyl chlorides under mild conditions in the ecofriendly solvent 2-methyltetrahydrofuran

An efficient continuous flow sequential synthesis of diaryl ketones was achieved by coupling of aryl Grignard reagents with acyl chlorides in the bio-derived “green” solvent 2-methyltetrahydrofuran (2-MeTHF) under mild reaction conditions (ambient temperature, 1 hour), allowing a safe and on-demand generation of 2-(3-benzoylphenyl)propionitrile with a productivity of 3.16 g hour?1

Oligothiophene-linked bisnaphthopyrans: Sequential and temperature- dependent photochromism

Photochromic bisnaphthopyrans linked with oligothiophenes were synthesized and their photochromic behavior studied. Sequential and temperature-dependent photochromism was observed in the oligothiophene linked bisnaphthopyrans. The kinetics of photo and thermal processes in bisnaphthopyrans in comparison with naphthopyrans were studied, Substituent and linking effects on the photochromic properties are discussed. We demonstrate that the cross-talk between the two photochromophores is dependent on the length of the oligothiophene linker. The presence of the bithiophene linker led to high colorability and high quantum yield of coloration.

Direct Formation of (Haloaryl)copper Nucleophiles from Haloiodobenzenes and Active Copper

(o-Halophenyl)-, (m-halophenyl)-, and (p-halophenyl)copper reagents have been formed in moderate to high yields at room temperature from active copper and the corresponding haloiodobenzenes.These reagents have been cross-coupled with a variety of alkyl and acyl halides to produce the respective haloarenes and haloaryl ketones.Remarkably, (o-fluorophenyl)- and (o-chlorophenyl)copper are produced in good yields by this procedure without undergoing elimination to form benzyne making this approach a convenient method for generating o-halophenyl nucleophiles.