69339-77-1

Basic information

• Product Name: 1,2,3-trihydronaphthyl radical
• Synonyms: 1,2,3-trihydronaphthyl radical
• CAS NO: 69339-77-1
• Molecular Weight: 131.197
• Mol File: 69339-77-1.mol

Chemical Properties

• CAS DataBase Reference: 1,2,3-trihydronaphthyl radical(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2,3-trihydronaphthyl radical(69339-77-1)
• EPA Substance Registry System: 1,2,3-trihydronaphthyl radical(69339-77-1)

Safety Data

• Hazardous Substances Data: 69339-77-1(Hazardous Substances Data)

Upstream product

• 119-64-2 tetralin 
• 4985-62-0 phenylthiyl 

Downstream Products

• 119-64-2 tetralin 
• 120-12-7 anthracene 
• 85-01-8 phenanthrene 
• 447-53-0 1,2-Dihydronaphthalene 
• 1154-13-8 1,1'-bitetralyl 
• 101-81-5 Diphenylmethane 
• 38899-49-9 monobenzyl-1,2,3,4-tetrahydronaphthalene 
• 108-88-3 toluene 

Relevant articles and documents

Evaluation of dissociation energies of S-H bonds in thiophenols and thioalcohols on the basis of kinetic measurements

Kinetic data on the reactions of alkyl and benzyl radicals with thiophenol C6H5SH were analyzed within the framework of the parabolic model of transition state. The values of the parameter that establishes a correlation between the activation energy of a reaction and its enthalpy were calculated for reactions of alkyl and benzyl radicals with the C6H5SH. The equations of the parabolic model were used to calculate the bond dissociation energies for 11 thiophenols and 4 thioalcohols. The activation energies for reactions of 12 thiophenoxy radicals with cumene and of C6H5S? radical with several alkyl-aromatic hydrocarbons were obtained.

Absorption Spectra and Photochemical Rearrangements of Alkyl- and Dialkylbenzene Cations in Solid Argon

Matrix photoionization of alkyl- and dialkylbenzenes produced and trapped the parent radical cations.Irradiation in the visible parent cation absorption induced α-H transfer to the cation ring to give substituted methylenecyclohexadiene cations.The ease of 1,3-hydrogen transfer in these experiments suggests that this may be an important rearrangement in gaseous alkylbenzene cations.Subsequent ultraviolet photolysis of these samples produced substituted styrene cations.