693810-52-5

Upstream product

• 100-52-7 benzaldehyde 
• 693810-51-4 N-((2S,3R,4R,5S,6R)-4,5-Dihydroxy-6-hydroxymethyl-2-methoxy-tetrahydro-pyran-3-yl)-2-iodo-benzamide 
• 609-67-6 2-Iodobenzoyl chloride 
• 1078691-95-8 (+)-D-glucosamine hydrochloride 

Downstream Products

• 693810-53-6 N-((4aR,6S,7R,8R,8aS)-8-Allyloxy-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl)-2-iodo-benzamide 
• 693810-50-3 methyl 3-O-allyl-4,6-di-O-benzyl-2-deoxy-2-(2-iodobenzoylamino)-α-D-glucopyranoside 
• 693810-54-7 N-((2S,3R,4R,5S,6R)-4-Allyloxy-5-hydroxy-6-hydroxymethyl-2-methoxy-tetrahydro-pyran-3-yl)-2-iodo-benzamide 

Relevant academic research and scientific papers

A new 20-membered macrocyclic dilactam: An unexpected product of a tri-n-butyltin hydride-mediated radical reaction

The tri-n-butyltin hydride-mediated reaction of methyl 3-O-allyl-4,6-di-O- benzyl-2-deoxy-2-(2-iodobenzoylamino)-α-D-glucopyranoside affords an unexpected benzomacrodilactam. The structure of this new 20-membered macrocyclic dilactam has been elucidated by electrospray mass and tandem mass spectrometry (ESI-MS/MS) and by 1H, 13C NMR spectroscopy, COSY, TOCSY, HMQC and HMBC experiments.