6943-13-1

Upstream product

• 106-44-5 p-cresol 
• 613-84-3 2-hydroxy-5-methylbenzaldehyde 
• 107-15-3 ethylenediamine 

Relevant academic research and scientific papers

Synthesis, crystal structure and antimicrobial activity of a hetero trinuclear manganese(III)-iron(II) complex derived from N,N'-bis(5-methylsalicylidene)-1,2-diaminoethane

A new hetero trinuclear manganese(III)-iron(II) complex, [Mn(salen)(H2O)]2[Fe(CN)6], in which salen is the dianionic form of N,N'-bis(5-methylsalicylidene)-1,2-diaminoethane, has been prepared and characterized by elementa

Synthesis and crystal structures of N,N'-bis(5-methylsalicylidene)ethane-1,2-diamine and its bromido-, phenolato-, and dicyanoamido-cobridged polymeric copper(II) complex

A bis-Schiff base N,N'-bis(5-methylsalicylidene)ethane-1,2-diamine (H2L) was prepared and characterized by elemental analysis, 1H NMR and 13C NMR spectra, MS, and single crystal X-ray diffraction (CIF file CCDC no. 1022761

Synthesis, Structure, and Catalytic Epoxidation Property of a New Phenolato and μ1,1,3-Azido Co-Bridged Polynuclear Manganese(III) Complex Derived from N,N′-Bis(5-methylsalicylidene)ethane-1,2-diamine

A new phenolato and 1,1,3-azido co-bridged polynuclear manganese(iii) complex has been synthesised and characterised. The structure of the complex has been confirmed by single crystal X-ray diffraction analyses. The ability of the complex to catalyse the

Improving the single-molecule magnet properties of two pentagonal bipyramidal Dy3+compounds by the introduction of both electron-withdrawing and -donating groups

Two mononuclear Dy3+compounds [Dy(bmbpen-F)X] (X = Cl,1; Br,2) with a pentagonal bipyramidal (PBP) geometry were obtained fromN,N′-bis-(5-methyl-2-hydroxybenzyl)-N,N′-bis(5-fluoro-2-methylpyridyl)ethylenediamine (H2bmbpen-F) and dysp

Influences of polarizability effect of alkyl group and homoring competition effect of substituents on the NMR spectra of salen-type Schiff base

Salen-type Schiff bases are a kind of important compounds and are widely used. In order to explore the effect of alkyl groups and substituents attached to aromatic ring on the chemical shifts, 63 title compounds were synthesized. Their 1H NMR and 13C NMR spectra were obtained; and the effects of the alkyl chain length and substituents on the chemical shifts (δH(CH=N), δC(CH=N), δH(OH), and δC(C-OH)) were studied. The results show that (1) the alkyl polarizability effect index (PEI) has an important influence on the chemical shifts of the above four atoms, with the increase of PEI, the values of δH(CH=N) and δc(CH=N) decrease, and the values of δH(OH) and δC(C-OH) increase. (2) The influence of substituent X attached to aromatic ring on the chemical shift is related to its position by taking OH or CH=N as reference. As for the effect of substituent on the chemical shifts, the effect of Hammett constant σ(X)-OH and excited-state substituent parameter (Formula presented.) with OH as reference are different from that ofσ(X)-CH=N and (Formula presented.) with CH=N as reference, and there is a “homoring competition effect” of the substituent. (3) The effect of the cross-interaction between X and OH on the chemical shift is also significantly different due to the different position of X. Quantitative correlation equations against chemical shifts were built for the four atoms, and the stability and prediction ability of the obtained equations were confirmed by leave-one-out cross validation.

Alteration of electronic effect causes change in rate determining step: Oxovanadium(IV)–salen catalyzed sulfoxidation of phenylmercaptoacetic acids by hydrogen peroxide

Sulfoxidation of a series of phenylmercaptoacetic acids (PMAA) by hydrogen peroxide catalysed by oxovanadium(IV)–salen complexes has been carried out spectrophotometrically in 100% acetonitrile medium. The formation and involvement of hydroperoxovanadium(

Nickel(II) Complexes Derived from Bis-Schiff Bases: Synthesis, Crystal Structures, and Antimicrobial Activity

Abstract: Nickel(II) complexes derived from the bis-Schiff bases N,N'-bis(5-methylsalicylidene)-1,2-diaminocyclohexane (H2La), N,N'-bis(5-methylsalicylidene)-1,2-diaminoethane (H2Lb) and N,N’-bis(3,5-difluorosal

Solvent-Dependent Bending Ability of Salen-Derived Organic Crystals

The formation of plastic or brittle organic crystals of salen derivatives that depend on the solvents employed for crystallization is demonstrated. Large yellow crystals (ranging from mm to cm size) of ten different salen derivatives were obtained and inv

Excess axial electrostatic repulsion as a criterion for pentagonal bipyramidal DyIII single-ion magnets with high: U eff and T B

In this work, a large excess of electrostatic repulsion, arising from the axial ligands, over that from the equatorial ligands is taken as the design strategy for high performance pentagonal bipyramidal (PBP) DyIII single-ion magnets (SIMs). In

Synthesis, X-ray crystal structures, and antibacterial activities of Schiff base nickel(II) complexes with similar tetradentate Schiff bases

Two new mononuclear complexes, [NiL1] · CH3OH (I) and [NiL2] (II), have been prepared from the tetradentate Schiff bases N,N'-bis(5-methylsalicylidene)ethylenediamine (H2L1) and N,N'-bis(5-methylsalic