694520-62-2

Upstream product

• 191274-51-8 (R)-4,4-diphenyl-5-benzyloxazolidin-2-thione 
• 97039-78-6 (4S,5S)-(+)-hydroxy-5 nonanolide-4 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 433268-11-2 Acetic acid (S)-5-[(S)-1-(tert-butyl-dimethyl-silanyloxy)-pentyl]-tetrahydro-furan-2-yl ester 
• 694520-57-5 (R)-N-acetyl-4,4-diphenyl-5-benzyloxazolidin-2-thione 
• 21685-51-8 D-phenylalanine methyl ester 
• 57728-37-7 (R)-(+)-2-amino-1,1,3-triphenyl-1-propanol 
• 433268-15-6 (S)-5-[(S)-1-(tert-Butyl-dimethyl-silanyloxy)-pentyl]-tetrahydro-furan-2-ol 

Downstream Products

• 909699-54-3 4-Nitro-benzoic acid (1R,4R)-5-benzyloxy-1-{(2S,5S)-5-[(S)-1-(tert-butyl-dimethyl-silanyloxy)-pentyl]-tetrahydro-furan-2-ylmethyl}-5-(R)-oxiranyl-4-triethylsilanyloxy-pentyl ester 
• 909699-55-4 4-Nitro-benzoic acid (1S,4R)-5-benzyloxy-1-{(2S,5S)-5-[(S)-1-(tert-butyl-dimethyl-silanyloxy)-pentyl]-tetrahydro-furan-2-ylmethyl}-5-(R)-oxiranyl-4-triethylsilanyloxy-pentyl ester 
• 909534-04-9 (2S,5R)-6-Benzyloxy-1-{(2S,5S)-5-[(S)-1-(tert-butyl-dimethyl-silanyloxy)-pentyl]-tetrahydro-furan-2-yl}-6-(R)-oxiranyl-5-triethylsilanyloxy-hexan-2-ol 
• 909534-03-8 (R)-6-Benzyloxy-1-{(2S,5S)-5-[(S)-1-(tert-butyl-dimethyl-silanyloxy)-pentyl]-tetrahydro-furan-2-yl}-6-(R)-oxiranyl-5-triethylsilanyloxy-hexan-2-one 
• 909534-02-7 (R)-1-Benzyloxy-6-{(2S,5S)-5-[(S)-1-(tert-butyl-dimethyl-silanyloxy)-pentyl]-tetrahydro-furan-2-yl}-1-(R)-oxiranyl-hex-4-yn-2-ol 

Relevant academic research and scientific papers

Contribution to the total synthesis of caribenolide I

Stereoselective synthesis of C13-C29 fragment of caribenolide I, a potent antitumour macrolide isolated from a marine dinoflagellate Amphidinium sp. is described. The key step relies on a highly diastereoselective C-glycosylation, us

Highly Diastereoselective Synthesis of trans-2,5-Disubstituted Tetrahydrofurans

trans-2,5-Disubstituted tetrahydrofurans were obtained as major diastereomers (trans / cis ratio 90:10-100: 0) when acetylated y-lactols derived from (S)-glutamic acid were treated with titanium enolates of N-acetyl (R)-oxazolidin-2-thiones. A simple tran