69563-88-8

Usage

Uses

Used in Environmental Applications:
2,2-Bis[4-(4-aminophenoxy)phenyl]hexafluoropropane is used as a precursor in the preparation of permeable membranes for atmospheric CO2 capture and gas transport. Its role in this application is crucial for developing efficient and selective gas separation technologies, which are essential for mitigating greenhouse gas emissions and addressing climate change.
Used in Polymer Industry:
In the polymer industry, 2,2-Bis[4-(4-aminophenoxy)phenyl]hexafluoropropane is utilized for the preparation of polyimide materials. Polyimides are high-performance polymers known for their exceptional thermal stability, mechanical properties, and chemical resistance. The incorporation of 2,2-Bis[4-(4-aminophenoxy)phenyl]hexafluoropropane into polyimide materials can potentially enhance their performance characteristics, making them suitable for applications in aerospace, electronics, and other high-tech industries where robust materials are required.

Hazard

Moderately toxic by ingestion and skin contact. An eye irritant.

InChI:InChI=1/C27H20F6N2O2/c28-26(29,30)25(27(31,32)33,17-1-9-21(10-2-17)36-23-13-5-19(34)6-14-23)18-3-11-22(12-4-18)37-24-15-7-20(35)8-16-24/h1-16H,34-35H2

Upstream product

• 1478-61-1 4,4'-(hexafluoroisopropylidene)diphenol 
• 100-00-5 4-chlorobenzonitrile 

Downstream Products

• 118569-70-3 1,1,1,3,3,3-hexafluoro-2,2-bis[4-(4-maleimidophenoxy)phenyl]propane 
• 383426-53-7 2,2-bis[N-(2-nitrophenyl)-{4-(4-aminophenoxy)phenyl}]hexafluoropropane 
• 137349-84-9 (Z)-3-{4-[4-(1-{4-[4-((Z)-3-Carboxy-acryloylamino)-phenoxy]-phenyl}-2,2,2-trifluoro-1-trifluoromethyl-ethyl)-phenoxy]-phenylcarbamoyl}-acrylic acid 

Relevant academic research and scientific papers

Synthesis process of 2-bis [4-(4-aminophenoxy) phenyl] hexafluoropropane

The invention relates to the technical field of 2, 2-bis [4-(4-aminophenoxy) phenyl] hexafluoropropane, in particular to a synthesis process of 2-bis [4-(4-aminophenoxy) phenyl] hexafluoropropane. Themethod comprises the following steps: dissolving hexafluorobisphenol A in a mixed solvent of dimethylformamide and benzene, adding potassium carbonate, carrying out reflux dehydration, adding 4-nitrochlorobenzene for reflux, filtering and precipitating to obtain 2, 2-bis [4- (4-nitrophenoxy) phenyl] hexafluoropropane, dissolving the 2, 2-bis [4-(4-nitrophenoxy) phenyl] hexafluoropropane into monohydric alcohol, refluxing with hydrazine hydrate under the catalysis of ferric trichloride and an activated carbon reduction catalyst, cooling and filtering to obtain the 2, 2-bis [4- (4-aminophenoxy)phenyl] hexafluoropropane. By comparing six embodiments, the treatment time of the sixth embodiment is the longest, but the yield of 2, 2-bis [4-(4-aminophenoxy) phenyl] hexafluoropropane is the highest, the safety of the technological process is higher, and the working experience of workers is improved.

2. 2 - b (4 - (4 - aminophenoxy) phenyl) hexafluoropropane and intermediate preparation method (by machine translation)

The invention provides a preparation method for a 2,2-bis(4-(4-aminophenoxyl)phenyl)hexafluoropropane intermediate. The intermediate is 2,2-bis(4-(4-nitrophenoxyl)phenyl)hexafluoropropane which is prepared by reacting 2,2-bis(4-hydroxyphenyl)hexafluoropropane with para halogenated nitrobenzene in the presence of a solvent, a catalyst and organic base. The invention further provides a preparation method for 2,2-bis(4-(4-aminophenoxyl)phenyl)hexafluoropropane. The method is implemented at low temperature, wherein a first-step reaction is carried out at 95 to 100 DEG C and a second-step reaction is carried out at 20 to 40 DEG C. Meanwhile, waste water is not produced in the process of treatment, so the method is friendly to environment. The method can improve product yield, above 79.9%, guarantee high product purity, as high as more than 99.7%, and reduce production cost.

A low-temperature process for preparing 2, 2 - di (4 - (4 - aminophenoxy) phenyl) hexafluoropropane and intermediates thereof

The present invention provides a method for preparing a 2,2-di(4-(4-aminophenoxy)phenyl)hexafluoropropane intermediate body at a low temperature. 2,2-di(4-hydroxylphenyl)hexafluoropropane and para-halogenated nitrobenzene are reacted in the presence of a solvent, a catalyst and copper powder to obtain 2,2-di(4-(4-nitrylphenoxy)phenyl)hexafluoropropane. The present invention further provides a method for preparing the 2,2-di(4-(4-aminophenoxy)phenyl)hexafluoropropane at a low temperature. According to the method, a reaction can be carried out at the low temperature and can be realized at 20-40 DEG C; and the reaction time is short and the preparation of the intermediate body can be finished by only 10 hours. By virtue of the method provided by the present invention, the yield of products can be increased and is higher than 79.9%, and the purity of the product is high and is higher than 99.7%; and meanwhile, the production cost is reduced.

A low-temperature quick preparation of 2, 2 - di (4 - (4 - aminophenoxy) phenyl) hexafluoropropane and intermediates thereof

The invention provides a method for low temperature rapid preparation of a 2, 2-bis(4-(4-aminophenoxy)phenyl)hexafluoropropane intermediate. The 2, 2-bis(4-(4-aminophenoxy)phenyl)hexafluoropropane intermediate is 2, 2-bis(4-(4-nitrophenoxy)phenyl)hexafluoropropane, and is obtained by reacting 2, 2-bis(4-(4-hydroxyphenyl)hexafluoropropane with para-halogenated nitrobenzene in the presence of a solvent, a catalyst A and alkali. The invention also provides the method for low temperature rapid preparation of 2, 2-bis(4-(4-aminophenoxy)phenyl)hexafluoropropane. The method provided by the invention adopts low temperature operation, and can complete the intermediate preparation after 8h of reaction at 65-80DEG C. The method can improve the product yield to over 78%, and also can reduce the production cost.

Thermoplastic resin composition and a method of molding the same

This invention provides a thermoplastic resin composition comprising a thermoplastic resin and 0.1 to 100 parts by weight, per 100 parts by weight of the thermoplastic resin, of an imide compound prepared, e.g., by dehydration condensation of 1,2,3,4-butanetetracarboxylic acid or a monoanhydride or a dianhydride thereof with a primary amine, and a method of molding the resin composition.

Polymers prepared from 4,4'-bis-[2-(3,4-(dicarboxyphenyl) hexafluoroisopropyl] diphenyl ether dianhydride

The application relates to fluorine-containing polyimides, polyamide-acids/esters, polyamides, addition polyimides and imide oligomers which exhibit low melting points, better solubilities, low dielectric constants, superior thermal and thermal oxidative stability, and improved processing characteristics. The products of this application are characterized by the fact that they are derived from 4,4'-bis[2-(3,4-(dicarboxyphenyl)-hexafluoroisopropyl]diphenyl ether dianhydride.