69573-35-9Relevant academic research and scientific papers
Metalated nitrile and enolate chlorinations
Pitta, Bhaskar Reddy,Fleming, Fraser F.
supporting information; experimental part, p. 2810 - 2813 (2010/08/07)
(Figure presented) Metalated nitriles and enolates rapidly and efficiently abstract chlorine from 2-chloro-2-fluoro-2-phenylacetonitrile to afford a diverse range of chloronitriles and chloroesters. The method provides the first general anionic chlorinati
The reduction of α,β-unsaturated nitriles and α-halonitriles with sodium hydrogen telluride
Blay, Gonzalo,Cardona, Luz,Garcia, Begona,Lahoz, Luisa,Pedro, Jose R.
, p. 8611 - 8618 (2007/10/03)
Sodium hydrogen telluride reacts chemoselectively with α,β- unsaturated nitriles and α-halonitriles linked to aromatic and aliphatic substituents to corresponding saturated nitriles with good yields.
ONE-POT SYNTHESIS OF α-CHLORONITRILES FROM ARYLCARBONYL COMPOUNDS
Kiyooka, Syun-ichi,Fujiyama, Ryoji,Kawaguchi, Katsuhiko
, p. 1979 - 1980 (2007/10/02)
α-Chloronitriles are prepared by the reaction of arylcarbonyl compounds and trimethylsilyl cyanide with a stoichiometric amount of titanium tetrachloride in good yields.
