69637-66-7

Basic information

• Product Name: methyl 2-(cyclohex-2-en-1-yl)prop-2-enoate
• CAS NO: 69637-66-7
• Molecular Formula: C₁₀H₁₄O₂
• Molecular Weight: 166.217
• Mol File: 69637-66-7.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 226.1°C at 760 mmHg
• Flash Point: 105.6°C
• Density: 1.005g/cm³
• Vapor Pressure: 0.0835mmHg at 25°C
• Refractive Index: 1.481
• CAS DataBase Reference: methyl 2-(cyclohex-2-en-1-yl)prop-2-enoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2-(cyclohex-2-en-1-yl)prop-2-enoate(69637-66-7)
• EPA Substance Registry System: methyl 2-(cyclohex-2-en-1-yl)prop-2-enoate(69637-66-7)

Safety Data

• Hazardous Substances Data: 69637-66-7(Hazardous Substances Data)

Upstream product

• 1521-51-3 rac-3-bromocyclohexene 
• 292638-85-8 acrylic acid methyl ester 
• 69637-65-6 (2-Cyclohex-2-enyl-2-methoxycarbonyl-ethyl)-trimethyl-ammonium; iodide 
• 86428-48-0 (Z,E)-1-fluoro-1-methoxy-2-(phenylsulfinyl)-1-propene 
• 822-67-3 Cyclohex-2-enol 
• 3853-06-3 methyl 3-(dimethylamino)propionate 
• 69637-62-3 2-Cyclohex-2-enyl-3-dimethylamino-propionic acid methyl ester 

Downstream Products

• 16822-06-3 cis-3-methylenehexahydrobenzofuran-2-one 
• 60916-75-8 (3aR,7aR)-3-Methylene-3a,4,5,7a-tetrahydro-3H-benzofuran-2-one 
• 54109-55-6 2-Cyclohex-2-enyl-acrylic acid 

Relevant articles and documents

Conjugate Reduction of α,β-Acetylenic Ketones and Esters by Diisobutylaluminum Hydride-Hexamethylphosphoric Triamide

-

AN EASY AND EFFICIENT SYNTHESIS OF α-METHYLENE-γ,δ-UNSATURATED ESTERS FROM ALLYLIC ALCOHOLS

A new method for the regio- and stereo-specific introduction of an acrylic ester unit, via a one pot reaction is described.

USE OF METHYL 3-(N,N-DIMETHYLAMINO)PROPIONATE AS A SYNTHON FOR THE CONSTRUCTION OF α-METHYLENE γ-BUTYROLACTONES

The lithium enolate of methyl 3-(N,N-dimethylamino)propionate reacts with allylic halides to give alkylation products which may be converted into α-methylene γ-butyrolactones by a reaction sequence which includes iodolactonization among other simple steps.