3853-06-3 Usage
Uses
Methyl 3-(dimethylamino)propionate was used in the synthesis of lithium enolate via reaction with lithium diisopropylamide.
Check Digit Verification of cas no
The CAS Registry Mumber 3853-06-3 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 3,8,5 and 3 respectively; the second part has 2 digits, 0 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 3853-06:
(6*3)+(5*8)+(4*5)+(3*3)+(2*0)+(1*6)=93
93 % 10 = 3
So 3853-06-3 is a valid CAS Registry Number.
InChI:InChI=1/C6H13NO2/c1-7(2)5-4-6(8)9-3/h4-5H2,1-3H3
3853-06-3Relevant articles and documents
Tandem conjugate addition-aldol reaction to α,β-unsaturated esters and ketones using titanium amide
Hosomi, Akira,Yanagi, Toshiharu,Hojo, Makoto
, p. 2371 - 2374 (2007/10/02)
Titanium dialkylamide, readily available, adds to a α,β-unsaturated esters and ketones in a conjugate addition mode to give ester and ketone enolates, respectively, which are successively quenched with electrophiles such as aldehydes and acetals. The aldol products can be readily converted to the corresponding deaminated or dehydrated derivatives selectively.