69645-02-9Relevant articles and documents
Copper-Catalyzed Oxysulfenylation of Enolates with Sodium Sulfinates: A Strategy to Construct Sulfenylated Cyclic Ethers
Gao, Yinglan,Gao, Yang,Tang, Xiaodong,Peng, Jianwen,Hu, Miao,Wu, Wanqing,Jiang, Huanfeng
, p. 1158 - 1161 (2016)
A new copper-catalyzed oxysulfenylation reaction of enolates with sodium sulfinates has been disclosed. A series of sulfenylated heterocycles including four- and seven-membered cyclic ether were obtained in mild to good yields. This reaction is proposed to go through a radical process, and the sulfur radical (RS?) may be a reactive species.