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2-((p-tolylthio)methyl)tetrahydrofuran is a chemical compound with the molecular formula C12H18OS. It is a derivative of tetrahydrofuran, a heterocyclic organic compound, with a p-tolylthio group attached to the methylene carbon atom. The p-tolylthio group consists of a phenyl ring with a methyl group (p-tolyl) and a sulfur atom. 2-((p-tolylthio)methyl)tetrahydrofuran is characterized by its unique structure, which combines the properties of both tetrahydrofuran and the p-tolylthio group, making it a versatile building block in organic synthesis and potentially useful in the development of pharmaceuticals and other chemical applications.

69645-02-9

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69645-02-9 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 69645-02-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 6,9,6,4 and 5 respectively; the second part has 2 digits, 0 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 69645-02:
(7*6)+(6*9)+(5*6)+(4*4)+(3*5)+(2*0)+(1*2)=159
159 % 10 = 9
So 69645-02-9 is a valid CAS Registry Number.

69645-02-9Relevant academic research and scientific papers

Copper-Catalyzed Oxysulfenylation of Enolates with Sodium Sulfinates: A Strategy to Construct Sulfenylated Cyclic Ethers

Gao, Yinglan,Gao, Yang,Tang, Xiaodong,Peng, Jianwen,Hu, Miao,Wu, Wanqing,Jiang, Huanfeng

, p. 1158 - 1161 (2016)

A new copper-catalyzed oxysulfenylation reaction of enolates with sodium sulfinates has been disclosed. A series of sulfenylated heterocycles including four- and seven-membered cyclic ether were obtained in mild to good yields. This reaction is proposed to go through a radical process, and the sulfur radical (RS?) may be a reactive species.

A highly stereoselective synthetic method for cis-2- hydroxymethyl-6-alkyltetrahydropyrans

Mandai, Tadakatsu,Ueda, Masayuki,Kashiwagi, Kaori,Kawada, Mikio,Tsuji, Jiro

, p. 111 - 114 (2007/10/02)

A highly stereoselective synthetic method for cis-2-hydroxymethyl-6-alkyltetrahydropyrans is described by an intramolecular 1,4-addition of alcohol.

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