697-37-0

Basic information

• Product Name: 1-(1-PROPYNYL)CYCLOHEXANOL
• Synonyms: 1-(1-PROPYNYL)CYCLOHEXANOL;TIMTEC-BB SBB008936;1-(1-Propynyl)cyclohexanol,98+%;1-PROPYNL CYCLOHEXANOL;1-prop-1-ynylcyclohexan-1-ol;1-prop-1-ynylcyclohexanol;1-PROPYNL-1-CYCLOHEXANOL;1-PROPYNYL-1-CYCLOHEXANOL
• CAS NO: 697-37-0
• Molecular Formula: C₉H₁₄O
• Molecular Weight: 138.21
• Mol File: 697-37-0.mol
• Article Data: 8

Chemical Properties

• Melting Point: 47°C
• Boiling Point: 92°C 10mm
• Flash Point: 91-92°C/10mm
• Appearance: /
• Density: 0.98g/cm³
• Vapor Pressure: 0.0218mmHg at 25°C
• Refractive Index: 1.5
• PKA: 13.28±0.20(Predicted)
• BRN: 1856828
• CAS DataBase Reference: 1-(1-PROPYNYL)CYCLOHEXANOL(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(1-PROPYNYL)CYCLOHEXANOL(697-37-0)
• EPA Substance Registry System: 1-(1-PROPYNYL)CYCLOHEXANOL(697-37-0)

Safety Data

• Statements: 10
• Safety Statements: 16-26-36
• RIDADR: 1325
• Hazardous Substances Data: 697-37-0(Hazardous Substances Data)

Usage

InChI:InChI=1/C9H14O/c1-2-6-9(10)7-4-3-5-8-9/h10H,3-5,7-8H2,1H3

Upstream product

• 16466-97-0 1-propynylmagnesium bromide 
• 108-94-1 cyclohexanone 
• 4529-04-8 1-propynyl lithium 
• 19135-08-1 1-(prop-2-ynyl)cyclohexanol 
• 74-99-7 prop-1-yne 

Downstream Products

• 122200-74-2 5-cyclohexylidene-4-methyl-1-pentene 
• 1655-03-4 1-cyclohex-1-enyl-propan-1-one 
• 1655-05-6 1-(1-propynyl)cyclohexene 
• 79972-50-2 3-cyclohexylidene-N,N-dimethyl-2-methyl-2-propenamide 
• 21949-35-9 S-Methyl-S'-<1-cyclohexyliden-propen-(1)-yl-(2)>-dithiolcarbonat 
• 1231256-07-7 1-((E)-4-bromo-1-phenylpent-3-en-1-yn-3-yl)cyclohexanol 
• 1231256-16-8 1-((E)-4-bromo-1-(4-bromophenyl)pent-3-en-1-yn-3-yl)cyclohexanol 
• 1940-19-8 1-vinylcyclohexanol 
• 78961-62-3 1-methoxy-1-(prop-1-yn-1-yl)cyclohexane 

Relevant articles and documents

SUBSTITUTED IMIDAZOLECARBOXYLATE DERIVATIVES AND THE USE THEREOF

A compound is shown in formula (I). The derivatives of the compound include a stereoisomer, a pharmaceutically acceptable salt, a solvate, a prodrug, a metabolite, a deuterated derivative. The compound is a structurally novel substituted imidazole formate derivative. Substituted imidazole formate derivatives are used in preparing a drug with sedative, hypnotic and/or anesthetic effects, as well as a drug that can control the state of epilepsy. The compound has a good inhibitory effect on the central nervous system, and provides a new option for clinical screening of and/or preparation of a drug with sedative, hypnotic and/or anesthetic effects and controlling the state of epilepsy.

Synthesis of 4-Oxoisoxazoline N-Oxides via Pd-Catalyzed Cyclization of Propargylic Alcohols with tert-Butyl Nitrite

A cyclization of propargylic alcohols with tert-butyl nitrite at room temperature in air was achieved using Pd(OAc)2 as catalyst. The first reported 4-oxoisoxazoline N-oxides could be directly accessed from a range of multisubstituted propargylic alcohols in moderate to excellent yields under mild conditions. Density functional theory calculations indicated that the reaction proceeds through a palladium-catalyzed NO2 addition that efficiently generates a ketoxime radical, which eventually produces 4-oxoisoxazoline N-oxide.

Palladium-Catalyzed Cascade C?O Cleavage and C?H Alkenylation of Phosphinyl Allenes: An Expeditious Approach to 3-Alkenyl Benzo[b]phosphole Oxides

A phosphine oxide-directed intramolecular cyclization of phosphinyl allenes is established for the first time. The palladium-catalyzed intramolecular cyclization provides an unprecedented cascade C?O cleavage and direct C?H alkenylation toward novel 3-alk