69765-77-1

Upstream product

• 10330-18-4 S-Ethyl-S-phenyl-N-p-tolylsulfonyl-sulfilimin 
• 51207-25-1 ethylphenylsulfoxide 
• 55962-05-5 [N-(p-tolylsulfonyl)imino]phenyliodinane 
• 42153-74-2 S-methyl-S-phenyl-N-(p-tolylsulfonyl)sulfoximide 
• 74-88-4 methyl iodide 

Downstream Products

• 82753-95-5 C₁₅H₁₅Cl₂NO₃S₂ 
• 82754-00-5 C₁₅H₁₅Br₂NO₃S₂ 
• 1097193-00-4 N-((1-fluoroethyl)(oxo)(phenyl)-λ⁶-sulfaneylidene)-4-methylbenzenesulfonamide 
• 87181-03-1 C₂₁H₂₅NO₄S₃ 
• 87181-01-9 C₁₅H₁₅NO₄S₃ 
• 345290-85-9 C₁₅H₁₆ClNO₃S₂ 

Relevant academic research and scientific papers

Efficient synthesis and ring-opening reactions of monofluorinated epoxides derived from α-fluorosulfoximines

Monofluorinated epoxides were successfully prepared through the O-cyclization reaction between α-fluorosulfoximines and ketones. The obtained fluoroepoxides were found to readily undergo an interesting ring-opening process (involving both a C-F bond cleavage and another C-F bond formation) in the presence of titanium tetrafluoride or pyridinium poly(hydrogen fluoride) to afford α-fluorinated ketones. The later process constitutes a formal catalytic 1,2-fluorine shift reaction.

Cu(I)-catalyzed sulfoximination

The reaction of PhI=NTs with sulfoxides in the presence of catalytic amounts of CuOTf afforded the corresponding N-tosylsulfoximines in high yield. The use of enantiomerically pure sulfoxides allowed stereoselective access to N-tosylsulfoximines with comp

A CONVENIENT PREPARATION OF N-(ARENESULFONYL)SULFOXIMINES BY OXIDATION OF N-(ARENESULFONYL)SULFILIMINES WITH SODIUM HYPOCHLORITE IN A TWO PHASE SYSTEM

N-(Arenesulfonyl)sulfilimines can be oxidized to the corresponding sulfoximines in high yields with sodium hypochlorite in an AcOEt-H2O two phase system in the presence of quaternary ammonium salts as catalysts.