700-56-1

Basic information

• Product Name: 2-METHYLADAMANTANE
• Synonyms: 2-METHYLADAMANTANE;Tricyclo[3.3.1.13,7]decane, 2-methyl-
• CAS NO: 700-56-1
• Molecular Formula: C₁₁H₁₈
• Molecular Weight: 150.26
• Product Categories: Adamantane derivatives
• Mol File: 700-56-1.mol
• Article Data: 8

Chemical Properties

• Boiling Point: 200.2 °C at 760 mmHg
• Flash Point: 59.2 °C
• Appearance: /
• Density: 0.942 g/cm³
• Refractive Index: 1.536
• CAS DataBase Reference: 2-METHYLADAMANTANE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-METHYLADAMANTANE(700-56-1)
• EPA Substance Registry System: 2-METHYLADAMANTANE(700-56-1)

Safety Data

• Hazardous Substances Data: 700-56-1(Hazardous Substances Data)

Usage

Purification Methods

Purify it by zone melting, chromatography through an Al2O3 column and eluting with pentane. Recrystallise it from EtOH and sublime it repeatedly at 90-95o/12mm. [Schleyer & Nicholas J Am Chem Soc 83 182 1961, Molle et al. Can J Chem 65 2428 1987.]

InChI:InChI=1/C9H13NO/c1-10(2)8-6-4-5-7-9(8)11-3/h4-7H,1-3H3

Upstream product

• 71904-70-6 tricyclo[5.2.1.0^4,10]dec-exo-2-ylcarbinol 
• 71904-70-6 tricyclo[5.2.1.0^4,10]dec-endo-2-ylcarbinol 
• 86831-64-3 2-(phenylthio)-2,4-methanoadamantane 
• 1660-04-4 1-acetyladamantane 
• 67-56-1 methanol 
• 119971-87-8 (1S^*,4S^*,8S^*)-Tricyclo<6.3.0.0^1,4>undecane 
• 82131-63-3 endo-2,8-trimethylene-cis-bicyclo<3.3.0>octan-9-ol 
• 82131-62-2 endo-2,8-trimethylene-cis-bicyclo<3.3.0>octan-8-ol 
• 70950-41-3 2-methyltriamantane 
• 14449-43-5 2-(n-butyl)adamantane 
• 30541-56-1 adamantylidene-adamantane 
• 14451-87-7 2-ethyladamantane 
• 7314-85-4 2-adamantyl bromide 
• 75-16-1 methylmagnesium bromide 

Downstream Products

• 281-23-2 adamantane 

Relevant articles and documents

Catalytic Ketone Hydrodeoxygenation Mediated by Highly Electrophilic Phosphonium Cations

Ketones are efficiently deoxygenated in the presence of silane using highly electrophilic phosphonium cation (EPC) salts as catalysts, thus affording the corresponding alkane and siloxane. The influence of distinct substitution patterns on the catalytic effectiveness of several EPCs was evaluated. The deoxygenation mechanism was probed by DFT methods.

Novel Rearrangement of 5,6-Disubstituted Bicyclooctan-2-ones with AlCl3. Application to Total Synthesis of (+/-)-5-Oxosilphiperfol-6-ene and (+/-)-Silphiperfol-6-ene

The acid-catalyzed rearrangement of bi- and tricyclic cyclobutyl ketones 8-20 having a bicyclooctan-2-one moiety with AlCl3 was studied to elucidate the scope and limitations of the novel rearrangement by which the tricyclic ketone 1 gave the angul

ACID CATALYZED RING CONTRACTIONS IN ENDO-2,8-TRIMETHYLENE-CIS-BICYCLOOCTYL CATIONS TO METHYLPERHYDROTRIQUINACENES. ONE OF THE METHYL EXTRUSION PROCESSES IN THE TRICYCLOUNDECANE REARRANGEMENT

Sulfuric acid catalyzed ring contractions with extrusion of a methyl group were examined for alcohol and olefin derivatives (28-31) of endo-2,8-trimethylene-cis-bicyclooctane (11), which was one of the two possible progenitors, among altogether 69