70196-21-3Relevant academic research and scientific papers
Synthesis and characterization of [Rh(PP)(PP)]X complexes (PP = DPPE or DPPP, X = Cl? or BF4-). Phosphine exchange and reactivity in transfer hydrogenation conditions
Mannu, Alberto,Vlahopoulou, Gina,Kubis, Christoph,Drexler, Hans-Joachim
, p. 59 - 64 (2019/02/20)
The synthesis of heteroleptic monomeric cationic Rh(I) bis-diphosphine complex [Rh(dppe)(dppp)]Cl (dppe = 1,2-bis-(diphenylphosphino)ethane and dppp = 1,3-bis-(diphenylphosphino)propane) was achieved by reaction between the neutral dimeric complex [Rhsub
Rhodium(I) complexes containing a bulky pyridinyl N-heterocyclic carbene ligand: Preparation and reactivity
Wang, Chao-Yu,Liu, Yi-Hong,Peng, Shei-Ming,Liu, Shiuh-Tzung
, p. 4012 - 4020 (2007/10/03)
Coordination chemistry of a new pyridine imidazole-2-ylidene ligand (pyN∧C) system with sterically hindered substituents toward rhodium(I) metal ions has been investigated. The rhodium complex [(pyN∧C)RhCl(COD)] (COD = 1,5-cyclooctad
CATIONIC COMPLEXES OF RHODIUM(I) CATALYSTS IN THE HOMOGENEOUS O2-OXIDATION OF TERMINAL ALKENES TO METHYL KETONES
Bressan, Mario,Morandini, Franco,Morvillo, Antonio,Rigo, Pierluigi
, p. 139 - 146 (2007/10/02)
+, + and + complexes are effective as catalysts for the oxidation by dioxygen of terminal olefins to methyl ketones.The complexes act as monooxygenases, the second oxygen atom being transferred to the alcohol solvent
