702-16-9

Usage

Synthesis Reference(s)

Tetrahedron Letters, 6, p. 129, 1965 DOI: 10.1016/S0040-4039(00)89940-2

InChI:InChI=1/C10H15N/c1-3-4-5-10-7-6-9(2)11-8-10/h6-8H,3-5H2,1-2H3

Upstream product

• 103028-77-9 2-methyl-5-butyrylpyridine 
• 50407-37-9 3-Butyl-2,4-dichlor-6-methylpyridin 
• 77202-08-5 4-methyl-1,2,3-triazine 
• 91027-97-3 5-Butyl-2-methyl-pyridin-3-carbonsaeure 
• 6967-70-0 3-n-Butyl-2,4-dihydroxy-6-methyl-pyridin 
• 57202-64-9 2-Butyl-3-dimethylamino-prop-2-enal 
• 91027-95-1 2-Dimethoxymethyl-1-dimethylamino-hex-1-en 
• 91027-96-2 5-Butyl-2-methyl-pyridin-3-carbonsaeureethylester 
• 3222-48-8 6-methylnicotinonitrile 
• 6960-22-1 6-methylnicotinamide 
• 21684-59-3 ethyl 6-methylnicotinate 
• 28051-70-9 methyl vinyl ketone oxime 
• 693-02-7 hex-1-yne 

Downstream Products

• 108-75-8 2,4,6-trimethyl-pyridine 
• 86873-66-7 5-n-Butyl-4-aminopyridin-2-carbonsaeure 
• 205313-17-3 (1-{(R)-1-{3-[(E)-2-(5-Butyl-pyridin-2-yl)-vinyl]-phenyl}-3-[2-(1-hydroxy-1-methyl-ethyl)-phenyl]-propylsulfanylmethyl}-cyclopropyl)-acetic acid methyl ester 
• 536-69-6 Fusaric acid 

Relevant academic research and scientific papers

Synthesis of pyridines from ketoximes and terminal alkynes via C-H bond functionalization

An expedient one-pot rhodium catalyzed C-H bond functionalization/ electrocyclization/dehydration procedure has been developed for the synthesis of highly substituted pyridine derivatives from terminal alkynes and α,β-unsaturated ketoximes. The use of electron-deficient phosphite ligands is important to suppress dimerization of the terminal alkynes to enynes.

DIELS-ALDER REACTION OF 1,2,3-TRIAZINE WITH ALDEHYDE ENAMINE

The Diels-Alder reaction of 4-methyl-1,2,3-triazine with several aldehyde enamines was carried out to afford 2,5-disubstituted pyridines.As an application of this method, we accomplished the synthesis of alkaloid, fusaric acid.