70223-10-8

Usage

InChI:InChI=1/C27H46O2/c1-17(2)7-6-8-18(3)21-9-10-22-20-16-25(29)24-15-19(28)11-13-27(24,5)23(20)12-14-26(21,22)4/h17-24,28H,6-16H2,1-5H3/t18-,19+,20+,21-,22+,23+,24?,26-,27-/m1/s1

Upstream product

• 82048-76-8 3-β-hydroxy-6-nitrocholest-5-ene 
• 82048-76-8 (10R,13R,17R)-17-((R)-1,5-Dimethyl-hexyl)-10,13-dimethyl-6-nitro-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-3-ol 
• 986-48-1 (5S,10R,13R,17R)-17-((R)-1,5-Dimethyl-hexyl)-3-hydroxy-10,13-dimethyl-hexadecahydro-cyclopenta[a]phenanthren-6-one oxime 
• 60-29-7 diethyl ether 
• 1250-95-9 5α,6α-epoxycholestan-3β-ol 
• 71-43-2 benzene 
• 5035-14-3 20β-amino-5α-pregnan-3β-ol 
• 75-77-4 chloro-trimethyl-silane 
• 1107-57-9 6α-nitrocholestan-3β-ol 

Downstream Products

• 2953-37-9 3β,5α-Dihydroxy-cholestan-6-on 
• 21066-07-9 3β-benzoyloxy-5α-cholestan-6-one 
• 1260-20-4 6α-phenyl-5α-cholestanediol-(3β,6β) 
• 80-97-7 Cholestanol 
• 21072-86-6 3α-chloro-5α-cholestan-6-one 
• 38404-75-0 cholestene-(5)-diyl-(3β.6)-dibenzoate 
• 83456-32-0 3β-p-toluenesulfonyloxy-5α-cholestan-6-one 
• 103396-99-2 6-p-tolyl-5α-cholestane-3β,6β-diol 
• 91414-15-2 3β-hydroxy-6-selenophenylcholest-5-ene 
• 5837-39-8 3β-methoxy-5α-cholestan-6-one 
• 5837-31-0 3β-methoxy-5β-cholestan-6-one 
• 28925-98-6 3β-acetoxy-6-phenyl-cholest-5-ene 
• 103390-43-8 acetic acid-(6β-hydroxy-6α-phenyl-5α-cholestanyl-(3β)-ester) 
• 481-21-0 cholestane 

Relevant academic research and scientific papers

Microwave-assisted transformation of α,β- and β,γ-unsaturated nitroalkenes into carbonyl compounds

Vinyl and allylic nitroalkenes have been converted into the corresponding carbonyl compounds in good yield using tin(II) chloride dihydrate under microwave irradiation.

Recation of Nitro-alkenes with Iodotrimethylsilane: A New Method for the Conversion of Vinyl Nitrosteroids to Ketosteroids

Iodotrimethylsilane generated in situ from chlorotrimethylsilane and sodium iodide effects the reduction of nitro-alkenes (1a-e) and (5) at -5 to O deg C to furnish the ketones (2a-e) and (6) respectively as the major products.

A Novel Method for Preparation of Steroidal Ketoximes from Nitroolefins

Steroidal 6-nitroolefins (I-IV) undergo facile reaction with NH3-MeOH-Zn yielding exclusively the corresponding 6-one oximes (V-VIII) in quantitative yields.The method appears to be of general applicability.

Steroids. Part 21. Photorearrangement of Steroidal Nitronate Salts and a N-Butyl Spiro-oxaziridine

Irradiation, at 254 nm, of ethanol solutions of nitro-steroids in the presence of an excess of sodium ethoxide gave a range of products including hydroxamic acids, ketones, and alkenes possibly derived from the anions of the N-hydroxyoxaziridines.Alternatively, the ketones and hydroxamic acids may be derived from the anions of the hydroxy-nitroso compounds.The proportions of products depend on the ring size and stereochemistry and the photoreactions differ significantly from those observed for N-alkyl spiro-oxaziridines including a steroidal N-butyl spiro-oxaziridine.