82048-76-8

Basic information

• Product Name: Cholest-5-en-3-ol, 6-nitro-, (3beta)-
• Synonyms: Cholest-5-en-3-ol, 6-nitro-, (3beta)-;6-nitrocholesterol
• CAS NO: 82048-76-8
• Molecular Formula: C₂₇H₄₅NO₃
• Molecular Weight: 0
• Mol File: 82048-76-8.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 536.7°C at 760 mmHg
• Flash Point: 197.2°C
• Appearance: /
• Density: 1.07g/cm³
• Vapor Pressure: 9.26E-14mmHg at 25°C
• Refractive Index: 1.537
• CAS DataBase Reference: Cholest-5-en-3-ol, 6-nitro-, (3beta)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cholest-5-en-3-ol, 6-nitro-, (3beta)-(82048-76-8)
• EPA Substance Registry System: Cholest-5-en-3-ol, 6-nitro-, (3beta)-(82048-76-8)

Safety Data

• Hazardous Substances Data: 82048-76-8(Hazardous Substances Data)

Usage

InChI:InChI=1/C27H45NO3/c1-17(2)7-6-8-18(3)21-9-10-22-20-16-25(28(30)31)24-15-19(29)11-13-27(24,5)23(20)12-14-26(21,22)4/h17-23,29H,6-16H2,1-5H3/t18-,19+,20+,21-,22+,23+,26-,27-/m1/s1

Upstream product

• 1912-54-5 3β-acetoxy-6-nitrocholest-5-ene 
• 99762-21-7 3β-acetoxy-6-nitro-7α-bromocholest-5-ene 
• 15505-91-6 5α-Chlor-6β-nitrocholestan-3β-ol 
• 604-35-3 Cholesteryl acetate 
• 1431-22-7 5-Chlor-6β-nitro-5α-cholestanol-(3β)-acetat 

Downstream Products

• 2953-37-9 3β,5-dihydroxy-5α-cholestan-6-one 
• 127514-63-0 6E-hydroximinocholestane-3β,5α-diol 
• 1175-06-0 (5S,10R,13R,17R)-17-((R)-1,5-Dimethyl-hexyl)-3-hydroxy-10,13-dimethyl-hexadecahydro-cyclopenta[a]phenanthren-6-one 
• 70223-10-8 6-ketocholestanol 
• 570-91-2 3β-hydroxycholest-4-en-6-one 
• 82033-55-4 6-nitrocholest-5-en-3β-yl tosylate 

Relevant articles and documents

Lithium Aluminium Hydride Reduction of Nitrosteroids

The reaction of 3β-acetoxy-6-nitro-7α-bromocholest-5-ene (1) with lithium aluminium hydride gave 6-nitrocholest-3,5-diene (2), 3β-acetoxy-5α-cholestan-6-one oxime (3), 3β-hydroxy-6β-nitrocholest-4-ene (4), 3β-hydroxy-6β-nitro-7α-bromocholest-4-ene (5), 3β-hydroxy-6-nitrocholest-5-ene (6) and 3β-hydroxy-6-aminocholest-5-ene (7).Under similar reaction conditions, 3β-chloro-6-nitro-7β-bromocholest-5-ene (8) afforded 3β-chloro-5β-cholestan-6-one oxime (9) and 3β-chloro-6-nitrocholest-5-ene (10).The structures of these compounds were established on the basis of their spectral data and comparison with authentic samples wherever available.

Steroid series. IX. A new route to 6-nitrosteroid derivatives.

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