70239-00-8Relevant academic research and scientific papers
Copper-catalyzed electrosynthesis of 1-acyl-2,2-diphenylcyclopropanes and their behaviour in acidic medium
Oudeyer, Sylvain,Léonel, Eric,Paugam, Jean Paul,Nédélec, Jean-Yves
, p. 1073 - 1081 (2007/10/03)
The formation of 1-acyl-2,2-diphenylcyclopropanes is performed under mild electrochemical conditions. These cyclopropane derivatives, through acid-catalyzed ring-opening, lead to γ,γ-diphenyl-β,γ-unsaturated carbonyl compounds which evolve into either substituted naphthalenes, or β-benzhydryl-α,β-cycloalkenones depending on the acyclic or cyclic nature of the intermediate allyl ketone.
General theoretical treatments of solid-state photochemical rearrangements and a variety of contrasting crystal versus solution photochemistry
Zimmerman, Howard E.,Zhu, Zhaoning
, p. 5245 - 5262 (2007/10/02)
In continuing our investigations of control of excited state reactivity by inclusion in crystal lattices, we have encountered a variety of new examples of differing reactivity resulting from lattice restraints. Different theoretical treatments were tested
