70284-20-7Relevant academic research and scientific papers
Synthesis of Fused Diaziridine Derivatives from Cyclic Secondary Amines by Utilizing N -Bromosulfonamides as an Aminating Reagent
Kiyosu, Yuuki,Tanaka, Shino,Okumura, Sota,Kiyokawa, Kensuke,Minakata, Satoshi
, p. 3101 - 3109 (2021/04/29)
The synthesis of a series of fused diaziridines, which are difficult to access by existing methods, was achieved by the reaction of cyclic secondary amines with p -toluenesulfonamide in the presence of N -bromosuccinimide (NBS) and a suitable base. This o
Efficient aziridination of olefins catalyzed by dirhodium catalysts
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Page/Page column 14, (2010/11/23)
This invention relates to compositions and methods for achieving the efficient aziridination of organic molecules, especially olefins. More specifically, the invention is directed to a mild, selective, and efficient aziridination protocol that involves catalysis by a mixed-valent dirhodium(II,III) catalyst (Rh25+). Especially preferred sources for forming such mixed-valent dirhodium(II,III) catalyst (Rh25+) are dirhodium(II) carboxamidates, such as dirhodium(II) caprolactamate, and their derivatives and analogues.
Efficient aziridination of olefins catalyzed by mixed-valent dirhodium(II,III) caprolactamate
Catino, Arthur J.,Nichols, Jason M.,Forslund, Raymond E.,Doyle, Michael P.
, p. 2787 - 2790 (2007/10/03)
(Chemical Equation Presented) A mild, efficient, and selective aziridination of olefins catalyzed by dirhodium(II) caprolactamate [Rh 2(cap)4·2CH3CN] is described. Use of p-toluenesulfonamide (TsNH2), N-bromosuc
