7030-75-3Relevant academic research and scientific papers
Stereoselective hydrosilylation of enals and enones catalysed by palladium nanoparticles
Benohoud, Meryem,Tuokko, Sakari,Pihko, Petri M.
supporting information; experimental part, p. 8404 - 8413 (2011/08/07)
A highly versatile and efficient hydrosilylation method by palladium nanoparticle catalysis allows the direct and chemoselective synthesis of 1)enolsilanes of high isomeric purity, 2)saturated aldehydes or ketones, or 3)the corresponding saturated acetals from α,β-unsaturated aldehydes or ketones. The choice of the product is determined by simply switching the solvent from THF to mixtures of THF/water or THF/alcohol. Copyright
Nickel-catalyzed coupling of alkenes, aldehydes, and silyl triflates
Ng, Sze-Sze,Ho, Chun-Yu,Jamison, Timothy F.
, p. 11513 - 11528 (2007/10/03)
A full account of two recently developed nickel-catalyzed coupling reactions of alkenes, aldehydes, and silyl triflates is presented. These reactions provide either allylic alcohol or homoallylic alcohol derivatives selectively, depending on the ligand em
