7042-08-2Relevant articles and documents
RuV-Acylimido Intermediate in [RuIV(Por)Cl2]-Catalyzed C–N Bond Formation: Spectroscopic Characterization, Reactivity, and Catalytic Reactions
Che, Chi-Ming,Hong, Dan-Yan,Huang, Jie-Sheng,Law, Siu-Man,Liu, Yungen,Lo, Vanessa Kar-Yan,Toy, Patrick H.,Wu, Liangliang
supporting information, p. 18619 - 18629 (2021/06/09)
Metal-catalyzed C?N bond formation reactions via acylnitrene transfer have recently attracted much attention, but direct detection of the proposed acylnitrenoid/acylimido M(NCOR) (R=aryl or alkyl) species in these reactions poses a formidable challenge. H
Asymmetric ring opening reactions of symmetrical N-acylaziridines with thiols catalyzed by chiral dialkyl tartrate-diethylzinc complexes
Hayashi, Masahiko,Ono, Kazuyuki,Hoshimi, Haruhisa,Oguni, Nobuki
, p. 7817 - 7832 (2007/10/03)
The asymmetric ring opening reaction of 1,2-(N-acylimino)cyclohexanes (N- acylaziridines) with some thiols proceeded in the presence of chiral zinc complexes prepared from diethylzinc and dialkyl L-(+)-tartrate to afford trans 2-(N-acylamino)-1-arylthiocyclohexane in up to 93% cc. The enantioselectivity is highly influenced by the molar ratio of the reactants and the nature of chiral dialkyl tartrate. The chemical structure of dialkyl L-(+)-tartrate-zinc complex is discussed on their 1H NMR spectra and molecular weight.