705263-87-2Relevant academic research and scientific papers
Preparation of monomeric [LAl(NH2)2] - A main-group metal diamide containing two terminal NH2 groups
Jancik, Vojtech,Pineda, Leslie W.,Pinkas, Jiri,Roesky, Herbert W.,Neculai, Dante,Neculai, Ana M.,Herbst-Irmer, Regine
, p. 2142 - 2145 (2004)
The reactions of [LA/Cl2] (L = HC[C(Me)N(Ar)]2, Ar = 2,6-iPr2C6H3) with NH3 or H 2O in the presence of a 1,3-di-tert-butylimidazol-2-ylidene as acceptor for the HCl lead to unique species of composition [LAl(NH 2)2] (depicted) or [LAl(OH)2], respectively. The by-product 1,3-di-tert-butylimidazolium chloride can be recovered by filtration and recycled to the corresponding carbene.
