70562-38-8

Upstream product

• 4712-55-4 diphenyl hydrogen phosphite 
• 882-33-7 diphenyldisulfane 
• 108-98-5 thiophenol 
• 2524-64-3 chlorophosphoric acid diphenyl ester 
• 2973-86-6 lithium thiophenoxide 
• 591-50-4 iodobenzene 
• 80141-24-8 Phosphorigsaeure-diphenyl-trimethylsilylester 

Downstream Products

• 1329686-47-6 C₁₉H₁₇ClNO₃P 
• 68036-35-1 (4-Methoxy-benzyl)-phosphoramidic acid diphenyl ester 
• 33985-75-0 phosphoramidic acid, N-(phenylmethyl)-, diphenyl ester 

Relevant academic research and scientific papers

Novel palladium-catalyzed thiophosphorylation of alkynes with phosphorethioate: An efficient route to (Z)-1-(diphenoxyphosphinyl)-2-(phenylthio)alkenes

Palladium complexes efficiently catalyze the addition of O,O,S-triphenyl phosphorothioate to terminal alkynes to produce (Z)-1-(diphenoxyphosphinyl)-2-(phenylthio)alkenes in high yields with high regio- and stereoselectivity.

Arylation of Axially Chiral Phosphorothioate Salts by Dinuclear PdI Catalysis

S-aryl phosphorothioates are privileged motifs in pharmaceuticals, agrochemicals, and catalysts; yet, the challenge of devising a straightforward synthetic route to enantioenriched S-aryl phosphorothioates has remained unsolved to date. We demonstrate herein the first direct C?SP(=O)(OR′)(OR′′) coupling of diverse and chiral phosphorothioate salts with aryl iodides, enabled by an air- and moisture-stable PdI dimer. Our mechanistic and computational data suggest distinct dinuclear PdI catalysis to be operative, which allows for operationally simple couplings with broad scope and full retention of stereochemistry.

Fast and transition metal-free general method for the preparation of chalcogenophosphates

In the presence of Cs2CO3 and I2, the coupling reaction of dialkyl phosphites with dichalcogenides (S, Se and Te) proceeds efficiently and completes in several minutes under mild conditions, affording the corresponding cha

N-Chlorosuccinimide-promoted synthesis of thiophosphates from thiols and phosphonates under mild conditions

A very simple N-chlorosuccinimide-promoted synthesis of thiophosphates through the coupling of thiols and phosphonates is reported. Notably, the reactions were carried out in the absence of a base. Functional groups including fluoro, bromo and trifluoromethyl are all tolerated by the reaction conditions employed. Both aryl and alkyl thiols are coupled smoothly with a broad spectrum of phosphonates to afford the corresponding thiophosphates in good to excellent yields.

Phosphorothioate-mercaptophosphonate rearrangement: Synthesis of new o-mercaptoaryl-and omercaptoheteroaryl phosphonates and their derivatives

New o-mercaptoaryl and o-mcrcaptohetcroaryl phosphonates and their derivatives were prepared via an ori/io-lithiation of O,O-diisopropyl S-aryl, 5-(2-pyridyl), S-(2-thienyl) and 5-(3-thienyl) phosphorothioates followed by a phosphonyl group S → C migration. Elsevier,.