70582-00-2Relevant articles and documents
Ion-molecule reactions of monosubstituted ethylsilylium ions with trimethyl(tert-butylamino)silane in the gas phase
Kochina,Shchukin,Nefedov,Sinotova
, p. 1233 - 1236 (2007/10/03)
Reaction of nuclear-chemically generated ethylsilylium ions with trimethyl(rert-butylamino)silane in the gas phase was studied. In the course of reaction the ethylsilylium ion completely isomerizes into the dimethylsilylium ion. Experiments show that the pathway involving proton transfer practically is not realized, in contrast to the reactions of carbenium ions with amines.