70593-68-9Relevant academic research and scientific papers
Bis(1-benzyl-4-aza-1-azoniabicyclo[2.2.2]octane) peroxodisulfate: A mild and efficient oxidant for oxidation of thiols, sulfides and aromatic amines to the corresponding disulfides, sulfoxides and azo compounds
Hajipour,Mohammadpoor Baltork,Kianfar
, p. 607 - 610 (2007/10/03)
Bis(1-benzyl-4-aza-1-azoniabicyclo[2.2.2]octane) peroxodisulfate (BAABCPS) 1, readily prepared as orange solid from commercially available 1,4-diazabicyclo[2.2.2]octane (DABCO) and potassium peroxodisulfate converts thiols, sulfoxides and aromatic amines to the corresponding disulfides, sulfoxides and azo compounds respectively.
An easy and efficient method for oxidation of alcohols and aromatic amines to the corresponding carbonyl and azo compounds under non-aqueous and neutral conditions
Hajipour, A. R.,Mahboobkhah, N.
, p. 285 - 287 (2007/10/03)
1-Benzyl-1-aza-4-azoniabicyclooctane periodate 1, readily prepared as an orange solid from commercially available 1,4-diazobicyclooctane, is useful for oxidation in anhydrous conditions.The reagent converts alcohols to die corresponding carbonyl compounds, α hydroxy ketones to diketones, and aromatic amines to azo compounds, in me excellent yields.The reagent ineffective in oxidising double bonds, aldehydes and ketones.
