70615-41-7Relevant academic research and scientific papers
Palladium-catalyzed C-N cross-coupling of N'-monosubstituted sulfondiimines with aryl bromides
Candy, Mathieu,Bohmann, Rebekka Anna,Bolm, Carsten
supporting information, p. 2928 - 2932 (2013/01/15)
A general method for the N-arylation of sulfondiimines with aryl bromides using tris(dibenzylideneacetone)dipalladium(0) [Pd2(dba)3] and 2-dicyclohexylphosphino-2′,6′-diisopropoxybiphenyl (RuPhos) as catalyst system was developed. A new benzothiazine was obtained, and a protocol for the cleavage of para-methoxyphenyl (PMP) groups in PMP-protected sulfondiimines has been found, which provides access to synthetically useful NH-derivatives, that are difficult to prepare by other means. Copyright
Synthesis of sulfondiimines by N-chlorosuccinimide-mediated oxidative imination of sulfiliminium salts
Candy, Mathieu,Guyon, Carole,Mersmann, Stefanie,Chen, Jia-Rong,Bolm, Carsten
supporting information; experimental part, p. 4440 - 4443 (2012/06/18)
Access to sulfondiimines: The oxidative one-pot chlorination-imination sequence of in situ generated free sulfilimines by N-chlorosuccinimide (NCS) allows the preparation of N-monosubstituted sulfondiimines under mild reaction conditions with excellent functional-group tolerance (see scheme; Mes=2,4,6-trimethylphenylsulfonyl) Copyright
CONVENIENT PREPARATION AND SPECTROSCOPIC STUDIES OF SULFOXIMINES AND SULFONEDIIMINES: N-CHLOROSULFILIMINE AS KEY INTERMEDIATE
Furukawa, Naomichi,Akutagawa, Kunihiko,Oae, Shigeru
, p. 1 - 14 (2007/10/02)
N-Unsubstituted sulfilimines, when reacted with sodium hypochlorite in an aqueous alkaline methanol solution or with Chloramine-T in dry acetonitrile in the presence of excess sodium salt of tosylamide were converted to the corresponding N-unsubstituted s
A FACILE CONVERSION OF SULFOXIMINES AND SULFONEDIIMINES TO SULFOXIDES AND SULFILIMINES WITH TERT-BUTYL NITRITE
Akutagawa, Kunihiko,Furukawa, Naomichi,Oae, Shigeru
, p. 369 - 374 (2007/10/02)
N-Unsubstituted sulfoximines and N-mono-tosylsulfonediimines were found to react readily with tert-butyl nitrite to give the corresponding sulfoxides and N-tosylsulfilimines in high yields with no racemization.
