N-tosyl-S-methyl-S-phenyl sulfondiimine

Base Information

• Chemical Name: N-tosyl-S-methyl-S-phenyl sulfondiimine
• CAS No.: 70615-41-7
• Molecular Formula: C₁₄H₁₆N₂O₂S₂
• Molecular Weight: 308.425
• Mol file: 70615-41-7.mol

Synonyms:N-tosyl-S-methyl-S-phenyl sulfondiimine

Chemical Property of N-tosyl-S-methyl-S-phenyl sulfondiimine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N-tosyl-S-methyl-S-phenyl sulfondiimine

There total 5 articles about N-tosyl-S-methyl-S-phenyl sulfondiimine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 44.0%

Phenyl-methyl-sulfilimin (42397-39-7) + chloroamine-T (127-65-1) → N-tosyl-S-methyl-S-phenyl sulfondiimine (70615-41-7)

Guidance literature:

With sodium p-toluenesulfonamide; In acetonitrile; at 40 ℃; for 24h;

Reference yield:

toluene-4-sulfonamide (70-55-3) + S-methyl-S-phenyl sulfiliminium mesitylenesulfonate → N-tosyl-S-methyl-S-phenyl sulfondiimine (70615-41-7)

Guidance literature:

S-methyl-S-phenyl sulfiliminium mesitylenesulfonate; With N-chloro-succinimide; sodium carbonate; In N,N-dimethyl-formamide; at 0 ℃; for 0.25h; Inert atmosphere;

toluene-4-sulfonamide; In N,N-dimethyl-formamide; at 20 ℃; for 12h; Inert atmosphere;

DOI:10.1002/adsc.201200754

Reference yield:

S-methyl-S-phenyl sulfiliminium mesitylenesulfonate → N-tosyl-S-methyl-S-phenyl sulfondiimine (70615-41-7)

Guidance literature:

Multi-step reaction with 2 steps

1: N-chloro-succinimide; sodium carbonate / N,N-dimethyl-formamide / 0.25 h / 0 °C / Inert atmosphere

2: N,N-dimethyl-formamide / 12 h / 20 °C / Inert atmosphere

With N-chloro-succinimide; sodium carbonate; In N,N-dimethyl-formamide;

DOI:10.1002/anie.201201296

upstream raw materials:

Phenyl-methyl-sulfilimin

sodium p-toluenesulfonamide

chloroamine-T

toluene-4-sulfonamide

Downstream raw materials:

S-methyl-S-phenyl-N-(p-tolylsulfonyl)sulfimide